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NCERT Exemplar · Q29

Q.The simple Bohr model is not applicable to He4\text{He}^4 atom because

(a) He4\text{He}^4 is an inert gas.
(b) He4\text{He}^4 has neutrons in the nucleus.
(c) He4\text{He}^4 has one more electron.
(d) electrons are not subject to central forces.
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The Bohr model works only for single‑electron systems. He4\text{He}^4 has two electrons, so the electron‑electron repulsion destroys the central‑force assumption — the correct reason is option (D).

The Bohr model is a beautiful, simple picture: an electron moves in a circular orbit around a point‑like nucleus, held by the Coulomb attraction. That works perfectly for hydrogen (one electron) and for ions like He+\text{He}^+, Li2+\text{Li}^{2+}, etc. — any system with exactly one electron.

But the moment you have two or more electrons, the story changes. Each electron feels not only the pull of the nucleus but also the push from every other electron. Those electron‑electron repulsions are not directed toward the nucleus — they are off‑centre, making the net force on any electron non‑central. The Bohr model’s entire foundation (a central, inverse‑square force) collapses.

Let’s go through the options one by one.

  1. Option (A): “He4\text{He}^4 is an inert gas.”

    Inertness is a chemical property — it tells you about bonding, not about the validity of a physical model. The Bohr model fails for helium not because it’s inert, but because it has two electrons. In fact, the Bohr model also fails for lithium, beryllium, etc. — none of which are inert. So this is a red herring.

  2. Option (B): “He4\text{He}^4 has neutrons in the nucleus.”

    Neutrons add mass but do not affect the Coulomb force (they are neutral). The Bohr model treats the nucleus as a point charge +Ze+Ze — the number of neutrons is irrelevant. He+\text{He}^+ (one electron) has the same neutrons and the Bohr model works perfectly for it. So this is not the reason.

  3. Option (C): “He4\text{He}^4 has one more electron.”

    This is almost correct — but it’s not the number of electrons alone that matters; it’s the fact that the extra electron introduces electron‑electron repulsion. The phrasing “one more electron” is vague. Compared to hydrogen, yes, helium has one more electron. But the Bohr model also fails for Li\text{Li} (two more electrons), Be\text{Be} (three more), etc. The key is that the forces are no longer central, not just the count.

  4. Option (D): “electrons are not subject to central forces.” …

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