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Exercise · Q25

Q.Using the same weak acid as in the worked example above (Ka=1.8×10−5K_a = 1.8 \times 10^{-5}), calculate its degree of ionization α\alpha in a more dilute, 0.01 M0.01\ \text{M} solution, and comment on how α\alpha changes on dilution.

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α≈Ka/C=(1.8×10−5)/(0.01)=1.8×10−3\alpha \approx \sqrt{K_a/C} = \sqrt{(1.8\times10^{-5})/(0.01)} = \sqrt{1.8\times10^{-3}}. Since 1.8≈1.342\sqrt{1.8} \approx 1.342 and 10−3≈0.03162\sqrt{10^{-3}} \approx 0.03162, α≈1.342×0.03162≈0.04243\alpha \approx 1.342 \times 0.03162 \approx 0.04243. Comparing with the earlier 0.1 M0.1\ \text{M} result (α≈0.0134\alpha \approx 0.0134), the ratio 0.0424/0.0134≈3.16≈100.0424/0.0134 \approx 3.16 \approx \sqrt{10} — exactly the factor expected from α∝1/C\alpha \propto 1/\sqrt{C} when …

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