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Example · Example 16

Q.Predict, with a reason, whether an aqueous solution of NaCl\text{NaCl} is acidic, basic or neutral.

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Concept understanding — Hydrolysis of Salts

Salt hydrolysis is the reaction of a salt's cation, anion, or both with water -- effectively the reverse of the neutralisation that formed the salt -- and it determines whether a salt solution ends up acidic, basic or neutral.

Strong acid + strong base (e.g. NaNO3NaNO_3): neither Na+Na^+ (conjugate acid of strong NaOHNaOH) nor NO3−NO_3^- (conjugate base of strong HNO3HNO_3) has any real tendency to react with water, so there is no hydrolysis and the solution stays neutral, pH = 7.

Strong base + weak acid, anionic hydrolysis (e.g. CH3COONaCH_3COONa): the anion CH3COO−CH_3COO^- (conjugate base of weak CH3COOHCH_3COOH) pulls a proton from water, CH3COO−+H2O⇌CH3COOH+OH−CH_3COO^-+H_2O \rightleftharpoons CH_3COOH+OH^-, so [OH−]>[H+][OH^-]>[H^+] and the solution is basic. The hydrolysis constant follows from multiplying this equilibrium by the acid's own KaK_a: Kh⋅Ka=KwK_h\cdot K_a=K_w, so Kh=Kw/KaK_h=K_w/K_a; with Kh=h2CK_h=h^2C (Ostwald-style), the resulting pH is pH=7+12pKa+12log⁡10CpH=7+\tfrac12pK_a+\tfrac12\log_{10}C. …

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