Q.Predict, with a reason, whether an aqueous solution of is acidic, basic or neutral.
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Start your 14-day free trial to unlock the full solution →Concept understanding — Hydrolysis of Salts
Salt hydrolysis is the reaction of a salt's cation, anion, or both with water -- effectively the reverse of the neutralisation that formed the salt -- and it determines whether a salt solution ends up acidic, basic or neutral.
Strong acid + strong base (e.g. ): neither (conjugate acid of strong ) nor (conjugate base of strong ) has any real tendency to react with water, so there is no hydrolysis and the solution stays neutral, pH = 7.
Strong base + weak acid, anionic hydrolysis (e.g. ): the anion (conjugate base of weak ) pulls a proton from water, , so and the solution is basic. The hydrolysis constant follows from multiplying this equilibrium by the acid's own : , so ; with (Ostwald-style), the resulting pH is . …
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