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Choose the Best Answer · Q11

Q.Choose the disproportionation reaction among the following redox reactions.

(a) 3Mg(s) + N₂(g) → Mg₃N₂(s)
(b) P₄(s) + 3NaOH + 3H₂O → PH₃(g) + 3NaH₂PO₂(aq)
(c) Cl₂(g) + 2KI(aq) → 2KCl(aq) + I₂
(d) Cr₂O₃(s) + 2Al(s) → Al₂O₃(s) + 2Cr(s)
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Step 1. (a) 3Mg + N2 → Mg3N2: Mg is oxidised (0→+2), N is reduced (0→-3) -- two DIFFERENT elements change, so this is a plain combination reaction, not disproportionation.

Step 2. (b) P4 + 3NaOH + 3H2O → PH3 + 3NaH2PO2: phosphorus starts at 0 (in P4) and ends up at −3 (in PH3, reduced) AND at +1 (in NaH2PO2, oxidised) -- the SAME element from the SAME starting compound splits into both a reduced and an oxidised product. This is disproportionation. …

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