Physics · Ch 11 — Thermodynamics
Refrigerators and their Efficiency (Qualitative)
Refrigerators and their Efficiency (Qualitative)
A refrigerator -- and, viewed from the opposite point of use, a heat pump used for heating -- is, in precise thermodynamic terms, nothing but a heat engine run backward. Instead of letting heat flow naturally from hot to cold in order to extract useful work, a refrigerator has external work deliberately supplied to it (typically by an electric compressor motor), and uses that work to force heat to flow the "wrong" way: it draws a quantity of heat out of a cold space -- the inside of the refrigerator cabinet, or the room being cooled by an air conditioner -- and rejects a larger quantity of heat, , to the warmer surroundings outside (the kitchen, or the outdoors). This is exactly, and unavoidably, the physical situation described by the Clausius statement of the second law (Section 11.9): heat never moves spontaneously "uphill," from a colder body to a hotter one, and doing so always demands that external work be supplied to force it.
Why only a qualitative idea is needed here. Unlike a heat engine, whose performance is naturally captured by an efficiency -- a fraction that is always less than one, telling us what portion of heat input becomes useful work -- a refrigerator's job is the opposite: it uses work to move heat, and a larger, not a smaller, amount of heat moved for a given amount of work supplied is what makes it a better refrigerator, not a worse one. So rather than an "efficiency" in the same sense as an engine, a refrigerator's performance is more naturally judged by how much heat it removes from the cold space for every unit of work it consumes -- and, at this qualitative level, simply understanding this trade-off, and how it changes with the temperatures involved, is the important physical idea.
For reference, this idea can be written compactly as a coefficient of performance, (the more heat removed per unit of work supplied, the higher, and better, this number is). For an ideal, reversible (Carnot) refrigerator working between the same two temperatures and as a Carnot engine, this can be shown to work out to
…