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Physics · Ch 11 — Thermodynamics

Refrigerators and their Efficiency (Qualitative)

11.13

Refrigerators and their Efficiency (Qualitative)

A refrigerator -- and, viewed from the opposite point of use, a heat pump used for heating -- is, in precise thermodynamic terms, nothing but a heat engine run backward. Instead of letting heat flow naturally from hot to cold in order to extract useful work, a refrigerator has external work WW deliberately supplied to it (typically by an electric compressor motor), and uses that work to force heat to flow the "wrong" way: it draws a quantity of heat Q2Q_2 out of a cold space -- the inside of the refrigerator cabinet, or the room being cooled by an air conditioner -- and rejects a larger quantity of heat, Q1=Q2+WQ_1 = Q_2 + W, to the warmer surroundings outside (the kitchen, or the outdoors). This is exactly, and unavoidably, the physical situation described by the Clausius statement of the second law (Section 11.9): heat never moves spontaneously "uphill," from a colder body to a hotter one, and doing so always demands that external work be supplied to force it.

Why only a qualitative idea is needed here. Unlike a heat engine, whose performance is naturally captured by an efficiency η=W/Q1\eta = W/Q_1 -- a fraction that is always less than one, telling us what portion of heat input becomes useful work -- a refrigerator's job is the opposite: it uses work to move heat, and a larger, not a smaller, amount of heat moved for a given amount of work supplied is what makes it a better refrigerator, not a worse one. So rather than an "efficiency" in the same sense as an engine, a refrigerator's performance is more naturally judged by how much heat it removes from the cold space for every unit of work it consumes -- and, at this qualitative level, simply understanding this trade-off, and how it changes with the temperatures involved, is the important physical idea.

For reference, this idea can be written compactly as a coefficient of performance, β=Q2/W\beta = Q_2/W (the more heat Q2Q_2 removed per unit of work WW supplied, the higher, and better, this number is). For an ideal, reversible (Carnot) refrigerator working between the same two temperatures T1T_1 and T2T_2 as a Carnot engine, this can be shown to work out to

βCarnot=T2T1−T2\beta_{\text{Carnot}} = \frac{T_2}{T_1 - T_2} …