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Example · Example 4

Q.Arrange the ligands I−\text{I}^-, H2O\text{H}_2\text{O}, NH3\text{NH}_3, and CN−\text{CN}^- in increasing order of ligand field strength according to the spectrochemical series.

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The spectrochemical series (Section 5.3) is an experimentally determined ranking of ligands by how strongly they split a metal's d-orbital energies. Locating each of the four given ligands on the series: I−\text{I}^- sits at the extreme weak-field end (large, highly polarizable halide ion, weak splitting); H2O\text{H}_2\text{O} sits in the intermediate region (a moderate-field neutral O-donor); NH3\text{NH}_3 sits further along, in the stronger-field region (moderate-to-strong N-donor); and CN−\text{CN}^- sits at the extreme strong-field end (one of the very strongest-splitting ligands known, alongside CO\text{CO}). Reading them off in the order the series places them gives the increasing-field-strength sequence directly. [!ANSWER] Increasing ligand field strength: I−<H2O<NH3<CN−\text{I}^- < \text{H}_2\text{O} < \text{NH}_3 < \text{CN}^-.

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