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Exercises · 15.12

Q.Write the monomers used for getting the following polymers.

(i) Polyvinyl chloride
(ii) Teflon
(iii) Bakelite
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  1. Polyvinyl chloride (PVC): an addition homopolymer of vinyl chloride (chloroethene), CH2=CHClCH_2=CHCl.

    n CH2=CHCl⟶−[−CH2−CHCl−]n−n\,CH_2=CHCl \longrightarrow -[-CH_2-CHCl-]_n-

  2. Teflon (PTFE): an addition homopolymer of tetrafluoroethene, CF2=CF2CF_2=CF_2, polymerised under high pressure with a peroxide catalyst. n CF2=CF2→peroxide, high pressure−[−CF2−CF2−]n−n\,CF_2=CF_2 \xrightarrow{\text{peroxide, high pressure}} -[-CF_2-CF_2-]_n- …

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