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Exercises · 15.3

Q.Distinguish between the terms homopolymer and copolymer and give an example of each.

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Homopolymer: a polymer formed from only one type of monomer unit, so all repeat units in the chain are identical.

Example: Polythene, −[−CH2−CH2−]n−-[-CH_2-CH_2-]_n-, formed entirely from ethene (CH2=CH2CH_2=CH_2) monomer units.

Copolymer: a polymer formed from two (or more) different types of monomer units, so the chain contains more than one kind of repeat unit, often arranged alternately or randomly.

Example: Buna-S, formed by copolymerisation of buta-1,3-diene (CH2=CH−CH=CH2CH_2=CH-CH=CH_2) and styrene (C6H5−CH=CH2C_6H_5-CH=CH_2).

Other examples: Nylon 6,6 (hexamethylenediamine + adipic acid) is also a copolymer, while Teflon (−[−CF2−CF2−]n−-[-CF_2-CF_2-]_n-, from tetrafluoroethene only) is another homopolymer.

✓Final answer

Homopolymer — single monomer, e.g. polythene (from ethene). Copolymer — two different monomers, e.g. Buna-S (buta-1,3-diene + styrene).

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