Exercises · 15.18
Q.Identify the monomer in the following polymeric structures.
(i) -[-C(=O)-(CH2)8-C(=O)-NH-(CH2)6-NH-]-n
(ii) a six-membered triazine ring bearing -NH- and -NH-CH2- substituents, linked by -CH2- bridges (a melamine-formaldehyde-type repeat unit)
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This repeat unit is that of Nylon-6,10, formed by condensation of two bifunctional monomers:
- Sebacic acid: (10 carbons total, contributing the portion)
- Hexamethylenediamine: (contributing the portion) with loss of water at each amide linkage.
(ii) The six-membered triazine ring bearing and substituents, linked by bridges
This repeat unit is characteristic of melamine-formaldehyde resin, formed by condensation of:
- Melamine (2,4,6-triamino-1,3,5-triazine), the triazine ring bearing three groups
- Formaldehyde: …
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