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Exercises · 15.18

Q.Identify the monomer in the following polymeric structures.

(i) -[-C(=O)-(CH2)8-C(=O)-NH-(CH2)6-NH-]-n
(ii) a six-membered triazine ring bearing -NH- and -NH-CH2- substituents, linked by -CH2- bridges (a melamine-formaldehyde-type repeat unit)
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(i) −[−C(=O)−(CH2)8−C(=O)−NH−(CH2)6−NH−]n−-[-C(=O)-(CH_2)_8-C(=O)-NH-(CH_2)_6-NH-]_n-

This repeat unit is that of Nylon-6,10, formed by condensation of two bifunctional monomers:

  • Sebacic acid: HOOC−(CH2)8−COOHHOOC-(CH_2)_8-COOH (10 carbons total, contributing the −C(=O)−(CH2)8−C(=O)−-C(=O)-(CH_2)_8-C(=O)- portion)
  • Hexamethylenediamine: H2N−(CH2)6−NH2H_2N-(CH_2)_6-NH_2 (contributing the −NH−(CH2)6−NH−-NH-(CH_2)_6-NH- portion) with loss of water at each amide linkage.

(ii) The six-membered triazine ring bearing −NH−-NH- and −NH−CH2−-NH-CH_2- substituents, linked by −CH2−-CH_2- bridges

This repeat unit is characteristic of melamine-formaldehyde resin, formed by condensation of:

  • Melamine (2,4,6-triamino-1,3,5-triazine), the triazine ring bearing three −NH2-NH_2 groups
  • Formaldehyde: HCHOHCHO …

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