Q.The threshold frequency for a certain metal is 3.3×1014 Hz. If light of frequency 8.2×1014 Hz is incident on the metal, predict the cut-off voltage for the photoelectric emission.
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🔒 Start your 14-day free trial to unlock the full solution →Concept understanding — Maximum Kinetic Energy
Maximum Kinetic Energy – From Intuition to Precision
Kinetic energy is the energy of motion: the faster something moves, the more kinetic energy it has. In many physical situations there is a maximum possible kinetic energy a particle can reach — set either by energy conservation or by an external energy constraint.
The Precise Statement
Kmax=21mvmax2
Where:
- Kmax = maximum kinetic energy (in joules)
- m = mass of the object (in kg)
- vmax = maximum speed reached (in m/s)
This formula alone doesn't tell you why there's a maximum — the physics lies in energy conservation or in an external constraint that limits the speed.
Where Does the Maximum Come From?
1. Energy conservation (no friction)
In a closed system, total mechanical energy E=K+U is constant, so
Kmax=E−Umin
The maximum kinetic energy occurs when the potential energy U is at its minimum — for example, a falling object is fastest (and U smallest) just before it lands.
2. External constraints (e.g., the photoelectric effect)
In modern physics, electrons in a metal absorb light energy. Each photon delivers a fixed energy hf. The electron must spend part of that energy escaping the metal (the work function ϕ); the rest becomes kinetic energy:
Kmax=hf−ϕ
Here the maximum is set entirely by the photon energy — no matter how intense the light, no single electron can gain more kinetic energy than this.
A Common Mistake
Students often think "maximum kinetic energy" means the fastest speed possible in the universe. It doesn't. The "maximum" is relative to the given system — the highest value under the stated conditions (height, spring compression, photon energy, and so on), not a universal speed limit. …
Why this formula?
Maximum Kinetic Energy — Why the Formula Holds
The idea of "maximum kinetic energy" appears in two very different contexts in your syllabus: photoelectric effect (modern physics) and simple harmonic motion (oscillations). I'll cover both, because the why is different in each case.
1. In the Photoelectric Effect
The formula you must know:
Kmax=hν−ϕ
where h is Planck's constant, ν is the frequency of incident light, and ϕ is the work function of the metal.
Why this formula? It comes from Einstein's photon model and energy conservation.
A single photon carries energy E=hν. When it strikes a metal surface, it can transfer all of its energy to one electron. That electron must first overcome the binding force holding it in the metal — the minimum energy needed for this is the work function ϕ. Any leftover energy becomes the electron's kinetic energy after it escapes.
So:
Photon energy = Energy to escape + Kinetic energy of ejected electron
hν=ϕ+K
If the electron just barely escapes (with zero kinetic energy), the photon frequency is the threshold frequency ν0, where hν0=ϕ.
For a higher frequency, the maximum kinetic energy an ejected electron can have is when it absorbs the photon's full energy and loses nothing to collisions inside the metal. That gives:
Kmax=hν−ϕ
Kmax does not depend on light intensity. Intensity only increases the number of electrons, not their maximum energy. This was the key puzzle that classical physics couldn't explain.
2. In Simple Harmonic Motion (SHM)
For a particle executing SHM, the maximum kinetic energy is:
Kmax=21mω2A2
where m is mass, ω is angular frequency, and A is amplitude.
Why this formula? It follows directly from the velocity equation.
In SHM, displacement is x=Asin(ωt+ϕ). Differentiating gives velocity:
v=dtdx=Aωcos(ωt+ϕ)
The velocity is maximum when cos(ωt+ϕ)=±1, i.e., at the equilibrium position (x=0):
vmax=Aω …
Concept: Maximum Kinetic Energy — The stopping potential V0 is directly related to the maximum kinetic energy of emitted photoelectrons by Kmax=eV0.
Step 1 — Einstein’s photoelectric equation gives:
Kmax=hν−hν0
where ν is the incident frequency and ν0 is the threshold frequency.
Step 2 — The cut-off (stopping) voltage V0 satisfies eV0=Kmax, so:
V0=eh(ν−ν0) …
The cut-off (stopping) voltage is found by equating the maximum kinetic energy of the emitted photoelectrons to the work done by the stopping potential. Using the photoelectric equation, the answer is 2.03 V.
Concept and Intuition
The photoelectric effect tells us that when light of sufficient frequency hits a metal surface, electrons are ejected. The energy of each incoming photon is hν. Part of this energy is used to overcome the metal's work function ϕ (the minimum energy needed to free an electron), and the rest becomes the kinetic energy of the emitted electron.
The maximum kinetic energy of the photoelectrons is given by Einstein's photoelectric equation:
Kmax=hν−ϕ
Now, the cut-off voltage (or stopping potential) V0 is the voltage that just stops the most energetic photoelectrons from reaching the other electrode. The work done by this voltage on an electron is eV0, and this must equal the maximum kinetic energy:
eV0=Kmax
So the problem reduces to: find Kmax from the given frequencies, then divide by e to get V0.
eV0=hν−hν0
where ν0 is the threshold frequency (since ϕ=hν0).
Step-by-step solution
-
Identify the given data
Threshold frequency: ν0=3.3×1014 Hz
Incident frequency: ν=8.2×1014 Hz
Planck's constant: h=6.63×10−34 J⋅s
Electron charge: e=1.6×10−19 C
-
Write the photoelectric equation for stopping potential
The maximum kinetic energy is:
Kmax=hν−hν0=h(ν−ν0)
And since eV0=Kmax, we have:
V0=eh(ν−ν0)
- Compute the frequency difference
ν−ν0=(8.2−3.3)×1014=4.9×1014 Hz
- Calculate the numerator h(ν−ν0)
h(ν−ν0)=(6.63×10−34)×(4.9×1014)
First multiply the numbers: 6.63×4.9=32.487 …
Method: Einstein's Photoelectric Equation
This is a direct application of Einstein's photoelectric equation, which connects the maximum kinetic energy of emitted electrons to the frequency of incident light and the work function of the metal.
Step 1: Recall the relevant formula
The maximum kinetic energy of a photoelectron is given by:
Kmax=hf−ϕ
where h is Planck's constant (6.63×10−34 J⋅s), f is the frequency of incident light, and ϕ is the work function of the metal.
The work function is related to the threshold frequency f0 by:
ϕ=hf0
The cut-off voltage V0 (also called stopping potential) is the voltage that just stops the most energetic photoelectrons, so:
Kmax=eV0
where e=1.6×10−19 C is the electron charge.
Step 2: Find the work function
ϕ=hf0=(6.63×10−34)(3.3×1014)
ϕ=2.1879×10−19 J
Step 3: Find the maximum kinetic energy
Kmax=hf−ϕ=(6.63×10−34)(8.2×1014)−2.1879×10−19
Kmax=5.4366×10−19−2.1879×10−19 …
Common Mistakes & How to Avoid Them
Mistake 1: Confusing cut-off voltage with stopping potential
Students often think cut-off voltage is something separate from stopping potential. It isn't. The cut-off voltage V0 is exactly the stopping potential — the minimum reverse voltage that stops the most energetic photoelectrons.
How to avoid: Remember that the cut-off voltage is defined by eV0=Kmax. When a question asks for cut-off voltage, it is asking for V0 from the photoelectric equation.
Mistake 2: Using the wrong formula or mixing up f and f0
The most common error is plugging numbers into Kmax=hf−ϕ but forgetting that ϕ=hf0. Then students either:
- Use hf0 as the kinetic energy directly, or
- Forget to subtract at all.
How to avoid: Always write the full photoelectric equation step by step:
Kmax=hf−hf0=h(f−f0)
Then eV0=Kmax, so V0=eh(f−f0).
Mistake 3: Unit errors with h and e
Students use h=6.63×10−34 J s but then forget that e=1.6×10−19 C gives V0 in volts only when Kmax is in joules. If you accidentally use h in eV·s, you must adjust accordingly.
How to avoid: Stick to SI units throughout:
- h=6.63×10−34 J s
- e=1.6×10−19 C
- Frequencies in Hz
- Answer V0 comes out in volts automatically
Mistake 4: Arithmetic errors with powers of 10
When subtracting 3.3×1014 from 8.2×1014, students sometimes mess up the exponent or misplace the decimal.
How to avoid: Do the subtraction inside the bracket first:
f−f0=(8.2−3.3)×1014=4.9×1014 Hz
Then multiply carefully: …
- AP EAPCET 2026Set eng-2026-05-13-FN1 markMCQQ.Work function of a metallic surface is 5.01 eV. When a light of wavelength 2000Å falls on the metallic surface, it emits photo electrons. The potential difference required to stop the fastest photo electron is? (in Volt) (A) 1.2 (B) 1.6 (C) 2.4 (D) 2.8
›Reveal solutionSolution
Using Einstein's photoelectric equation, the incident photon's energy (6.2 eV) minus the work function (5.01 eV) gives the maximum kinetic energy, and hence a stopping potential of about 1.2 V.
Concept and Intuition
Einstein's photoelectric equation states that the maximum kinetic energy of an emitted photoelectron equals the photon's energy minus the metal's work function:
KEmax=hν−ϕ=λhc−ϕ.
The stopping potential V0 is the retarding voltage that just brings the fastest photoelectrons to rest, so eV0=KEmax, giving V0 numerically in volts when energies are expressed in eV.
Step-by-Step Solution
- Photon energy using the handy constant hc≈12400 eV⋅A˚: E=200012400=6.2 eV.
- Work function given: ϕ=5.01 eV.
- Maximum kinetic energy: KEmax=E−ϕ=6.2−5.01=1.19 eV. …
- AP EAPCET 2026Set eng-2026-05-14-FN1 markMCQQ.Light of wavelength 1000A˚ incidents on a metal surface of work function 6 eV. The maximum kinetic energy of photoelectrons is (A) 12.4 eV (B) 6.4 eV (C) 19.2 eV (D) 0 eV
›Reveal solutionSolution
Einstein's photoelectric equation: KEmax=hc/λ−ϕ. With λ=1000A˚ and ϕ=6 eV, KEmax=6.4 eV.
Concept and Intuition
In the photoelectric effect, a single photon transfers all its energy to one electron. Part of that energy overcomes the metal's work function ϕ (the minimum energy needed to free the electron), and whatever is left over becomes the electron's kinetic energy — this is Einstein's photoelectric equation, KEmax=Ephoton−ϕ.
Step-by-Step Solution
- Convert wavelength: 1000A˚=1000×10−10m=100nm. …
- AP EAPCET 2026Set eng-2026-05-14-AN1 markMCQQ.When photons of energy 4.2 eV incident on a photosensitive material of work function 2.2 eV, photoelectrons are emitted with a maximum linear momentum of P. If photons of energy 6.2 eV incident on the same photosensitive material, the maximum linear momentum of the emitted photoelectrons is (A) 4 P (B) P2 (C) 2 P (D) P3
›Reveal solutionSolution
Uses Einstein's photoelectric equation to get the maximum kinetic energy, then the non-relativistic momentum-energy relation p=2mKE to compare momenta.
Concept and Intuition
The maximum kinetic energy of photoelectrons is KEmax=hν−ϕ, where hν is the photon energy and ϕ is the work function. Momentum and kinetic energy for a non-relativistic electron are related by p=2mKE, so momentum scales as the square root of kinetic energy, not linearly with photon energy.
Step-by-Step Solution
- First case: KE1=4.2eV−2.2eV=2.0eV, with momentum p1=2mKE1=P.
- Second case: KE2=6.2eV−2.2eV=4.0eV=2×KE1.
- Momentum ratio: p1p2=KE1KE2=2.
- So p2=2P. …
- AP EAPCET 2026Set ap-2026-05-20-FN1 markMCQQ.The energy of a photon of wavelength 2500 Å is 4.96 eV. When photons of wavelength 3100Å incident on a photosensitive material of work function 2.2 eV, the maximum velocity of the emitted photoelectrons is (Mass and charge of the electron are 9×10−31 kg and 1.6×10−19 C) (A) 4×106ms−1 (B) 4×105ms−1 (C) 8×106ms−1 (D) 8×105ms−1
›Reveal solutionSolution
This is a photoelectric effect problem: use the given photon-energy/wavelength pair to calibrate hc, then apply Einstein's photoelectric equation to find the maximum electron speed.
Concept and Intuition
Einstein's photoelectric equation says the maximum kinetic energy of an emitted photoelectron equals the incident photon's energy minus the material's work function: KEmax=λhc−ϕ. The problem first gives us a calibration point (2500 Å ↔ 4.96 eV) so we don't need to remember hc precisely — we can find the effective hc product from it.
Step-by-Step Solution
- From the given data: E=λhc⇒hc=4.96eV×2500A˚=12400eV⋅A˚ — this matches the well-known constant hc≈12400eV⋅A˚.
- Photon energy at 3100 Å: E′=310012400=4.0eV.
- Maximum kinetic energy of photoelectron: KEmax=E′−ϕ=4.0−2.2=1.8eV.
- Convert to joules: KEmax=1.8×1.6×10−19=2.88×10−19J. …
- AP EAPCET 2024Set eng-2024-05-18-FN1 markMCQQ.Energy required to remove an electron from aluminium surface is 4.2 eV. If light of wavelength 2000 Å falls on the surface, the velocity of the fastest electron ejected from the surface will be (A) 8.4×105 ms−1 (B) 7.4×105 ms−1 (C) 6.4×105 ms−1 (D) 8.4×106 ms−1
›Reveal solutionSolution
Applying Einstein's photoelectric equation with the given work function and photon wavelength gives a maximum kinetic energy of 2 eV, which corresponds to an electron speed of 8.4×105 m/s.
Concept and Intuition
The photoelectric effect: each photon transfers its entire energy hc/λ to one electron; the electron escapes only after "paying" the work function, with any leftover energy becoming kinetic energy.
Step-by-Step Solution
- Photon energy: E=λhc=200 nm1240 eV nm=6.2 eV.
- Maximum kinetic energy: KEmax=E−ϕ=6.2−4.2=2.0 eV =2.0×1.6×10−19=3.2×10−19 J. …
- AP EAPCET 2024Set eng-2024-05-21-AN1 markMCQQ.The maximum wavelength of light which causes photoelectric emission from a photosensitive metal surface is λ0. Two light beams of wavelengths 3λ0 and 9λ0 incident on the metal surface. The ratio of the maximum velocities of the emitted photoelectrons is (A) 3:4 (B) 1:3 (C) 1:2 (D) 2:3
›Reveal solutionSolution
Use Einstein's photoelectric equation with the threshold wavelength to find kinetic energies, then take the square root to get the velocity ratio. Answer: 1:2.
Concept and Intuition
Einstein's photoelectric equation gives the maximum kinetic energy of an emitted electron as KE=hc/λ−hc/λ0=hc(λ1−λ01), where λ0 is the threshold wavelength. Since KE=21mv2, the velocity ratio is the square root of the kinetic energy ratio.
Step-by-Step Solution
- For λ1=λ0/3: KE1=hc(λ03−λ01)=λ02hc.
- For λ2=λ0/9: KE2=hc(λ09−λ01)=λ08hc.
- KE1:KE2=2:8=1:4. …
- AP EAPCET 2024Set eng-2024-05-22-FN1 markMCQQ.The surface of a metal is first illuminated with a light of wavelength 300 nm and later illuminated by another light of wavelength 500 nm. It is observed that the ratio of maximum velocities of photo electrons in two cases is 3. The work function of metal value is close to (A) 6.48 eV (B) 1.23 eV (C) 4.17 eV (D) 2.28 eV
›Reveal solutionSolution
Photoelectric-effect problem with two wavelengths and a known ratio of max photoelectron speeds; eliminating the unknown work function via the ratio gives W≈2.28 eV.
Concept and Intuition
Einstein's photoelectric equation states 21mvmax2=λhc−W, where W is the work function. Given two different illuminating wavelengths, we get two equations in two unknowns (W and the electron's mass/velocity scale); the given velocity ratio lets us eliminate the common kinetic-energy scale factor and solve directly for W.
Step-by-Step Solution
- Let K1=21mv12 (for λ1=300 nm) and K2=21mv22 (for λ2=500 nm). Given v1/v2=3⇒K1/K2=9, so K1=9K2.
- Einstein's equations: 9K2=λ1hc−W and K2=λ2hc−W.
- Subtract: 8K2=λ1hc−λ2hc. …
- AP EAPCET 2023Set eng-2023-05-18-FN1 markMCQQ.Photoelectrons are emitted with maximum velocity v when light of frequency 3f incidents on a photosensitive material of work function 2hf. If the frequency of the incident light is 4.25f, the maximum velocity of the emitted photoelectrons is (h – Plank's constant) (A) 0.5 v (B) v (C) 1.5 v (D) 2 v
›Reveal solutionSolution
Using Einstein's photoelectric equation twice (once to find hf in terms of v, once to find the new velocity) gives v′=1.5v.
Concept and Intuition
Einstein's photoelectric equation, KEmax=hfincident−ϕ, lets us relate the maximum kinetic energy (hence maximum velocity) of photoelectrons to the incident frequency and the material's work function. Given data at one frequency lets us solve for the unknown constant hf, which can then be used at the new frequency.
Step-by-Step Solution
- At frequency 3f: 21mv2=h(3f)−2hf=hf.
- So hf=21mv2 — this is a useful relation we'll reuse.
- At frequency 4.25f: KE′=h(4.25f)−2hf=2.25hf. …
- AP EAPCET 2022Set ap-2022-07-12-AN1 markMCQQ.The photoemission of electrons occur when a light of frequency 5×1014 Hz is incident on a metal surface with work function of 2.0 eV. The maximum speed of emitted photoelectrons is approximately (Planck's constant =6.6×10−34 J-s, mass of electron =9×10−31 kg) (A) 25×105 m s−1 (B) 23×105 m s−1 (C) 325×105 m s−1 (D) 32×105 m s−1
›Reveal solutionSolution
Einstein's photoelectric equation gives the maximum kinetic energy of ejected electrons; converting to speed via KE=21mv2 gives vmax=325×105 m/s.
Concept and Intuition
Only photons with energy above the metal's work function can eject electrons; the excess energy hf−ϕ becomes the electron's kinetic energy. This is the foundational evidence for the particle (photon) nature of light.
Step-by-Step Solution
- Photon energy: hf=6.6×10−34×5×1014=3.3×10−19 J.
- Work function: ϕ=2.0eV=2.0×1.6×10−19=3.2×10−19 J.
- Maximum KE: KEmax=3.3×10−19−3.2×10−19=1.0×10−20 J.
- From KEmax=21mvmax2: vmax=9×10−312×1.0×10−20=2.222×1010.
- vmax≈1.4907×105 m/s. …
- AP EAPCET 2022Set eng-2022-07-06-FN1 markMCQQ.A radiation of 3.8 eV falls on a metal surface to produce photo electrons. These electrons are made to enter a magnetic field of 2×10−4 T. If the radius of the largest circular path followed by these electrons is 30 mm, then the work function of the metal is (Mass of electron me=9×10−31 kg) (A) 0.9 eV (B) 1.0 eV (C) 0.6 eV (D) 1.2 eV
›Reveal solutionSolution
The largest circular radius corresponds to the fastest (maximum kinetic energy) photoelectrons. Compute that KE from the magnetic-radius relation, then subtract from the photon energy via Einstein's photoelectric equation to get the work function.
Concept and Intuition
When photoelectrons enter a magnetic field, they move in circles of radius r=mv/(eB) (magnetic force provides centripetal force). Since v varies (electrons are ejected with a range of kinetic energies up to a maximum, set by Einstein's equation KEmax=hf−ϕ), the largest radius corresponds to the fastest electrons — i.e. the maximum kinetic energy. This lets us work backward from the given radius to KEmax, and then to the work function.
Step-by-Step Solution
- From r=eBmv: v=meBr.
- KEmax=21mv2=21m(meBr)2=2me2B2r2.
- Plug in: e=1.6×10−19 C, B=2×10−4 T, r=0.03 m, m=9×10−31 kg.
- e2B2r2=(2.56×10−38)(4×10−8)(9×10−4)=9.216×10−49. …
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