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Exercises · 5.21

Q.Describe some features of catalysis by zeolites.

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Step 1 – What zeolites are. Zeolites are hydrated aluminosilicates with a general open framework of (AlO4)(AlO_4) and (SiO4)(SiO_4) units, giving a honeycomb-like structure riddled with cavities and pores of fixed, uniform size (typically 260–740 pm).

Step 2 – Shape-selective action. The catalytic reaction depends on the size of the pores/cavities — only reactant molecules small enough to enter the pores (and products small enough to leave) take part. Hence zeolite catalysis is shape-selective catalysis.

Step 3 – Activation. They are activated by heating to remove the water of hydration, exposing the internal cavities where catalysis occurs. …

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