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Answer the following questions · Q16

Q.Explain the geometry of the methane molecule on the basis of hybridisation.

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Step 1. Excite carbon. Ground-state C is 1s22s22px12py12pz01s^22s^22p_x^12p_y^12p_z^0; one 2s electron is promoted to the empty 2pz2p_z orbital, giving four half-filled orbitals (2s, 2px2p_x, 2py2p_y, 2pz2p_z).

Step 2. Hybridize. These four orbitals mix and recast into four new, equivalent sp3 hybrid orbitals, identical in shape and energy, oriented for minimum mutual repulsion — which places them 109°28' apart, pointing toward the four corners of a regular tetrahedron.

Step 3. Bond formation. Each sp3 hybrid orbital, carrying one unpaired electron, overlaps axially with a hydrogen 1s orbital, forming one C-H sigma bond; this happens identically for all four hybrids, giving four equivalent (sp3-s) C-H sigma bonds. …

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