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Answer the following questions · Q19

Q.Which type of hybridization is present in the ammonia molecule? Write the geometry and bond angle present in ammonia.

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Step 1. Hybridization type. Nitrogen's ground state (1s22s22p31s^22s^22p^3) already has 3 unpaired electrons plus 1 lone pair; these four valence-shell electron groups mix into four sp3 hybrid orbitals.

Step 2. Bond formation. Three of the four sp3 hybrid orbitals (each singly occupied) overlap axially with a hydrogen 1s orbital, forming three N-H sigma bonds; the fourth sp3 orbital holds nitrogen's lone pair, uninvolved in bonding.

Step 3. Geometry. With 3 bonding pairs and 1 lone pair (VSEPR type AB3E, Table 5.4), the shape is trigonal pyramidal, not the fully regular tetrahedron a no-lone-pair AB4 species would show. …

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