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Chemistry · Class 11 Science

Ch 8Elements of Group 1 and 2 — Class 11 Chemistry, concept-first.

Groups 1 and 2 both belong to the s-block of the periodic table, since in every element of these two groups the last electron added enters an 's' subshell. Hydrogen, atomic number 1, is the very first element of the periodic table and sits at the top of group 1 alongside the alkali metals -- but because it differs from…

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Position of Hydrogen in the Periodic Table

Hydrogen has the electronic configuration , a single electron in its valence shell, which gives it a dual, anomalous character.

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Introduction

Groups 1 and 2 both belong to the s-block of the periodic table, since in every element of these two groups the last electron added enters an 's' subshell.

8.1

Hydrogen

Groups 1 and 2 both belong to the s-block of the periodic table, because in each of their elements the last (highest-energy) electron added enters an 's' subshell.

8.1.1

Occurrence

In its free (uncombined) state, hydrogen occurs as dihydrogen gas, H2. Hydrogen is the single most abundant element in the entire universe, making up roughly 70% of the universe's total mass, and it i…

8.1.2

Position of hydrogen in the periodic table

Where hydrogen belongs in the periodic table has long been debated, because its single-electron configuration, 1s¹, can be read two different ways.

8.1.3

Isotopes of Hydrogen

Isotopes are atoms of the same element — meaning they share the same number of protons, and so the same atomic number — that differ from one another in mass number because they carry different numbers…

8.1.4

Preparation of dihydrogen

Dihydrogen can be prepared by several routes, split broadly into laboratory-scale and industrial-scale methods. A.

8.1.5

Properties of dihydrogen

A. Physical properties: dihydrogen is a colourless, odourless, tasteless gas that burns with a pale blue flame; it is non-polar, essentially insoluble in water, and lighter than air. B.

8.1.6

Uses of dihydrogen

Dihydrogen's largest single industrial use is in manufacturing ammonia. It is also used to make vanaspati ghee by the catalytic hydrogenation of vegetable oils; as a rocket fuel in its liquefied form;…

8.2.1

Introduction

Groups 1 and 2 sit on the far left of the periodic table; in both, the last electron added enters an 's' subshell, which is why both belong to the s-block.

8.2.2

Electronic configuration of elements of group 1 and group 2

Every group 1 element has the general outer electronic configuration ns¹, and every group 2 element has ns².

8.2.3

Trends in atomic and physical properties of elements of group 1 and group 2

Both groups share a broad physical character: the alkali metals are silvery-white and soft, and because of their comparatively large atomic size they have low densities — they are, as a group, the mos…

8.2.4

Chemical properties of elements of group 1 and group 2

Both the alkali metals and the alkaline earth metals are highly reactive, which is exactly why they are always found in nature already combined with other elements rather than free.

8.2.5

Diagonal Relationship

It might be expected that every element within a single group should show a smooth, regular gradation of properties — but the first member of group 1 (lithium) and the first member of group 2 (berylli…

8.2.6

Uses of elements of group 1 and group 2

Group 1: lithium metal is used in the long-life batteries found in digital watches, calculators and computers; liquid sodium is used as a heat-transfer medium in nuclear power stations; potassium chlo…

8.2.7

Biological importance of elements of group 1 and group 2

Group 1: sodium ion is present in the largest supply of all ions in extracellular fluids, which serve as the medium that transports nutrients to the body's cells; the concentration of sodium ion in th…

8.3.1

Sodium Carbonate (washing soda) Na2CO3.10H2O

Sodium carbonate, familiar as washing soda, Na2CO3.10H2O, is manufactured commercially by the Solvay process.

8.3.2

Sodium hydroxide (caustic soda) NaOH

Sodium hydroxide, caustic soda, NaOH, is manufactured commercially by electrolysing a saturated aqueous solution of sodium chloride (brine) in a Castner-Kellner cell, which uses a mercury cathode and…

8.3.3

Calcium Carbonate (CaCO3)

Calcium carbonate, CaCO3, occurs naturally as chalk, limestone and marble. It can be prepared in two ways: (i) by bubbling carbon dioxide through a solution of calcium hydroxide (slaked lime), which p…

8.3.4

Hydrogen peroxide (H2O2)

Hydrogen peroxide, H2O2, is a low-cost, clean, mild oxidising agent, commercially sold as a 30% aqueous solution.

8.3.5

Lithium aluminium hydride (LiAlH4)

Lithium aluminium hydride, commonly abbreviated LAH, has the formula LiAlH4. It is prepared by reacting lithium hydride with aluminium chloride, 4LiH + AlCl3 → LiAlH4 + 3LiCl.

More questions

31 Q
+Show 2 questions2 questions
  1. Q30Collect the information of preparation of dihydrogen and make a chart.Free
  2. Q31Find out the s block elements compounds importance/uses.Preview
+Show 5 questions5 questions
  1. Q1Which is the first element in the periodic table ?Free
  2. Q2What are isotopes ?Free
  3. Q3Write the formulae of the compounds of hydrogen formed with sodium and chlorine.Preview
  4. Q4What is the name of the family of reactive metals having valancy one ?Preview
  5. Q5What is the name of the family of reactive metals having valancy two ?Preview
+Show 1 question1 question
  1. Q6In the chemical reaction 2Na(s) + H2(g) → 2NaH(s), which element does undergo oxidation and which does undergo reduction ?Preview
+Show 23 questions23 questions
  1. Q7Explain the following: Hydrogen shows similarity with alkali metals as well as halogens.Free
  2. Q8Explain the following: Standard reduction potential of alkali metals have high negative values.Free
  3. Q9Explain the following: Alkaline earth metals have low values of electronegativity; which decrease down the group.Free
  4. Q10Explain the following: Sodium dissolves in liquid ammonia to form a solution which shows electrical conductivity.Preview
  5. Q11Explain the following: BeCl2 is covalent while MgCl2 is ionic.Preview
  6. Q12Explain the following: Lithium floats an water while sodium floats and catches fire when put in water.Preview
  7. Q13Write balanced chemical equations for the following. CO2 is passed into concentrated solution of NaCl, which is saturated with NH3.Preview
  8. Q14Write balanced chemical equations for the following. A 50% solution of sulphuric acid is subjected to electrolyte oxidation and the product…Preview
  9. Q15Write balanced chemical equations for the following. Magnesium is heated in air.Preview
  10. Q16Write balanced chemical equations for the following. Beryllium oxide is treated separately with aqueous HCl and aqueous NaOH solutions.Preview
  11. Q17Answer the following questions. Describe the diagonal relationship between Li and Mg with the help of two illustrative properties.Preview
  12. Q18Answer the following questions. Describe the industrial production of dihydrogen from steam. Also write the chemical reaction involved.Preview
  13. Q19Answer the following questions. A water sample, which did not give lather with soap, was found to contain Ca(HCO3)2 and Mg(HCO3)2. Which che…Preview
  14. Q20Answer the following questions. Name the isotopes of hydrogen. Write their atomic composition schematically and explain which of these is ra…Preview
  15. Q21Name the following. Alkali metal with smallest atom.Preview
  16. Q22Name the following. The most abundant element in the universe.Preview
  17. Q23Name the following. Radioactive alkali metal.Preview
  18. Q24Name the following. Ions having high concentration in cell sap.Preview
  19. Q25Name the following. A compound having hydrogen, aluminium and lithium as its constituent elements.Preview
  20. Q26Choose the correct option. The unstable isotope of hydrogen is ..... a. H-1 b. H-2 c. H-3 d. H-4Preview
  21. Q27Choose the correct option. Identify the odd one. a. Rb b. Ra c. Sr d. BePreview
  22. Q28Choose the correct option. Which of the following is Lewis acid ? a. BaCl2 b. KCl c. BeCl2 d. LiClPreview
  23. Q29Choose the correct option. What happens when crystalline Na2CO3 is heated ? a. releases CO2 b. loses H2O c. decomposes into NaHCO3 d. colour…Preview