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Exercise · Q17

Q.Answer the following questions.
Describe the diagonal relationship between Li and Mg with the help of two illustrative properties.

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Step 1. Reaction with air. Lithium burns in air to give Li2O plus the nitride Li3N; magnesium burns in air to give MgO plus the nitride Mg3N2. This nitride-forming pattern is typical of group 2, not group 1 — the rest of group 1 (Na, K, …) give only oxide/peroxide/superoxide type products, with no nitride. So here Li behaves like a group-2 element, specifically like Mg.

Step 2. Thermal decomposition of the carbonate. On heating, Li2CO3 decomposes to Li2O + CO2, exactly as MgCO3 decomposes to MgO + CO2. By contrast, the carbonates of the rest of group 1 (Na2CO3, K2CO3, …) are thermally stable and do not decompose under comparable heating. Again, Li's behaviour matches Mg's rather than the rest of its own group. …

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