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Exercise · Q9

Q.Explain the following:
Alkaline earth metals have low values of electronegativity; which decrease down the group.

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✓ Free question

Step 1. Why electronegativity is low overall. Electronegativity measures an atom's tendency to attract a shared pair of electrons in a bond. Alkaline earth metals are strongly electropositive — they would rather lose their two ns² electrons entirely (to form M²⁺) than attract more electron density — so their electronegativity values are low across the whole group (roughly 1.5 down to 0.9, per Table 8.5).

Step 2. Why electronegativity falls further down the group. Going down the group, each successive element has one more occupied shell, so its valence electrons sit farther from the nucleus and are increasingly shielded by inner-shell electrons. A farther, more shielded outer shell is held less tightly, and so attracts a shared electron pair even less strongly — hence electronegativity decreases from Be (1.5) to Ba (0.9).

✓Final answer

Alkaline earth metals have low electronegativity because they are strongly electropositive metals that readily lose (rather than attract) electrons; electronegativity decreases down the group because atomic size increases and the outer electrons sit farther from, and are more shielded from, the nucleus.

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