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Solve the following problems · Q40

Q.Carbohydrates are compounds containing only carbon, hydrogen and oxygen. When heated in the absence of air, these compounds decompose to form carbon and water. If 310 g of a carbohydrate leave a residue of 124 g of carbon on heating in absence of air, what is the empirical formula of the carbohydrate ? (Ans.: CH2O)

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Step 1. 310 g of carbohydrate leaves 124 g of carbon on heating; the remaining 310−124=186310-124 = 186 g must be the water driven off (since carbohydrates contain only C, H and O, and decompose to carbon + water).

Step 2. Moles C =124/12=10.33= 124/12 = 10.33; moles H2O =186/18=10.33= 186/18 = 10.33. …

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