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Answer the following · Q12

Q.La belongs to group 3 while Hg belongs to group 12 and both belong to period 6 of the periodic table. Write down the general outer electronic configuration of the ten elements from La to Hg together using orbital notation method.

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Step 1. Identify the ten elements. In period 6, the elements occupying groups 3 to 12 are La(57), Hf(72), Ta(73), W(74), Re(75), Os(76), Ir(77), Pt(78), Au(79) and Hg(80) — the lanthanoid series (Ce to Lu, atomic numbers 58-71) is placed separately at the bottom of the table and is not counted among these ten (section 7.2).

Step 2. Recall the d-block general pattern. Section 7.3.3 gives the d-block's general outer configuration as ns0−2(n−1)d1−10ns^{0-2}(n-1)d^{1-10}; for period 6 this becomes 6s0−25d1−106s^{0-2}5d^{1-10}, filling from La's 6s25d16s^25d^1 up to Hg's 6s25d106s^25d^{10}.

Step 3. Note the known anomaly within this range. As worked out in Problem 7.3, Au (group 11) does not follow the plain pattern: its outer configuration is 6s15d106s^15d^{10} rather than the 'expected' 6s25d96s^25d^9, because a completely-filled 5d subshell is extra stable — exactly the same kind of exception noted for Cr and Cu in the period-4 d-block.

Step 4. State the overall pattern. Using orbital notation, the ten elements' outer configurations run: La 6s25d16s^25d^1, Hf 6s25d26s^25d^2, Ta 6s25d36s^25d^3, W 6s25d46s^25d^4, Re 6s25d56s^25d^5, Os 6s25d66s^25d^6, Ir 6s25d76s^25d^7, Pt 6s25d96s^25d^9 (Pt is also anomalous, favouring a near-filled d subshell), Au 6s15d106s^15d^{10}, Hg 6s25d106s^25d^{10}.

✓Final answer

The general outer configuration across La to Hg (period 6, groups 3-12) follows 6s0−25d1−106s^{0-2}5d^{1-10}, with individual anomalies such as Au (6s15d106s^15d^{10} instead of the plain-pattern 6s25d96s^25d^9) arising from the extra stability of a completely-filled d subshell.

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