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Explain the following · Q8

Q.Cu forms coloured salts while Zn forms colourless salts.

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Step 1. Recall the d-block colour rule. Section 7.4.3 states that the ability to form coloured ions is a property of d-block elements with PARTIALLY-filled inner d-orbitals; elements like Zn, Cd and Hg, whose d subshell is completely filled (ns2(n−1)d10ns^2(n-1)d^{10}), do NOT show this property.

Step 2. Check Cu's typical ion. Copper commonly forms Cu2+Cu^{2+}, with configuration [Ar]3d9[Ar]3d^9 — a partially-filled d subshell.

Step 3. Check Zn's typical ion. Zinc forms Zn2+Zn^{2+}, with configuration [Ar]3d10[Ar]3d^{10} — a completely-filled d subshell. …

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