Q.Cu (belongs to period 4 and group 11)
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Start your 14-day free trial to unlock the full solution →Step 1. Note the period and group. Cu is in period 4 (n=4) and group 11, in the d-block.
Step 2. Predict the plain Aufbau configuration. Following the straightforward filling order through period 4's d-block (Sc to Zn), Cu (the ninth d-block element) would be expected to have configuration .
Step 3. Apply the extra-stability exception. A COMPLETELY-filled d subshell () is significantly more stable than a configuration, so one electron shifts from 4s into 3d — exactly the same kind of anomaly the chapter notes for chromium (section 7.3.3), but resulting here in a fully-filled rather than a half-filled d subshell. …
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