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Chemistry · Ch 13 — Nuclear Chemistry and Radioactivity

Even-Odd Nature of Proton and Neutron Numbers

13.3.1

Even-Odd Nature of Proton and Neutron Numbers

Whether the proton count ZZ and neutron count NN of a nuclide are each individually even or odd turns out to be a strong predictor of nuclear stability. Tallying up the naturally occurring stable nuclides by this even/odd split gives four groups: 165 nuclides have both ZZ and NN even; 55 have ZZ even and NN odd; 50 have ZZ odd and NN even; and only 4 have both ZZ and NN odd.

Even-ZZ, even-NN nuclides make up about 85% of the mass of the Earth's crust, and their sheer abundance is itself the evidence that this combination is the most stable: protons tend to pair up with other protons, and neutrons with other neutrons, and these paired-up (even-even) configurations impart extra stability to the nucleus, much as paired electrons impart extra stability in atomic and molecular structure.

Where only one of ZZ or NN is odd, the count of stable nuclides drops to roughly a third of the even-even count -- 55 versus 50, which are nearly equal to each other. That near-equality is itself informative: it shows protons and neutrons behave similarly with respect to pairing and stability, since in either case exactly one nucleon (a proton in one group, a neutron in the other) is left without a same-type partner. …

Table 13.2Distribution of naturally occurring stable nuclides by even/odd Z and N

Table 13.2. Z even, N even: 165 such nuclides (about 85% of the Earth's crust) -- protons pair off with protons and neutrons pair off with neutrons, giving maximum stability. Z even, N odd: 55 such nuclides. Z odd, N even: 50 such nuclides -- the near-equal counts for these two 'one odd' rows show protons and neutrons behave similarly with respect to stability, since in each case one nucleon is left without a partner. Z odd, N odd: only 4 such nuclides (about 2% of the Earth's crust) -- having two separate unpaired nucleons (one proton, one …