Chemistry · Ch 13 — Nuclear Chemistry and Radioactivity
Transmutation
Transmutation
Section 13.7 turns from natural (spontaneous) nuclear changes -- alpha decay, beta decay -- to non-spontaneous, human-induced nuclear reactions, generally called nuclear transmutations.
Nuclear transmutation is the transformation of one stable nucleus into a different nucleus, whether that resulting nucleus is itself stable or unstable. Where the resulting product nucleus IS radioactive, the specific transmutation is given its own name: artificial (or induced) radioactivity (covered in section 13.7.2).
A nuclear reaction is fundamentally different in character from an ordinary chemical reaction, and the two are usefully contrasted point by point. A chemical reaction rearranges atoms via the breaking and forming of chemical bonds and only ever involves the outer-shell (valence) electrons, is accompanied by comparatively small energy changes, and its rate is sensitive to temperature, pressure, concentration and catalysts. A nuclear reaction, by contrast, actually converts one isotope or element into an entirely different one, can directly involve protons, neutrons and other elementary particles (not just electrons), releases vastly larger amounts of energy (the fission of just 1 g of uranium-235 releases about kJ, compared with only …
Table 13.3, five contrasts. (1) Chemical reactions rearrange atoms by breaking and forming chemical bonds; nuclear reactions convert an isotope of one element into another element altogether. (2) Different isotopes of an element behave chemically alike; isotopes of an element can behave very differently in a nuclear reaction. (3) Only outer-shell (valence) electrons take part in a chemical reaction; a nuclear reaction can additionally involve protons, neutrons and other elementary particles. (4) Chemical reactions are accompanied by relatively small energy changes -- e.g. burning 1.0 g of methane releases only about 56 kJ; nuclear reactions are accompanied by vastly larger energy changes -- e.g. the nuclear transformation of 1 g of uranium-235 releases about 8.2 x 10^7 kJ. (5) The rate of a chemical reaction is influenced by temperature, pressure, concentration and c …