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Chemistry · Ch 13 — Nuclear Chemistry and Radioactivity

Gamma Decay

13.6.3

Gamma Decay

Gamma (γ\gamma) radiation is high-energy electromagnetic radiation, and it is almost always emitted TOGETHER WITH an alpha or a beta decay, rather than occurring entirely on its own. The reason is that when a parent nucleus emits an alpha or beta particle, the resulting daughter nucleus is often left behind in an energetically EXCITED state, not immediately in its lowest-energy (ground) state; the daughter then relaxes down to its ground state by emitting the extra energy as one or more gamma-ray photons.

A concrete illustration from the source: uranium-238 decaying by alpha emission, 238238-9292-U→234U \rightarrow 234-9090-Th+4Th + 4-22-He+γHe + \gamma, is observed to emit alpha particles of two distinct energies -- 4.147 MeV (23% of decays) and 4.195 MeV (77% of decays). When the lower-energy alpha (4.147 MeV) is emitted, the resulting thorium-234 daughter is left in an excited state, and it de-excites down to its ground state by emitting a gamma-ray photon of energy 0.048 MeV -- accounting for the energy 'missing' from that lower-energy alpha branch com …

Misc Problem 13.6Counting alpha and beta particles emitted in 237-93-Np → 209-83-Bi

Worked out. Worked example. Since alpha-particle emission lowers the mass number by 4 while beta-particle emission does not change the mass number, the net drop in mass number (237 - 209 = 28) must come entirely from alpha emissions: number of alpha particles = 28/4 = 7. Each alpha particle also lowers the atomic number by 2, so 7 alpha particles alone would lower the atomic number by 14; but the actual observed drop in atomic number is only 93 - 83 = 10. The 'missing' increase of 14 - 10 = 4 must therefore come from beta emissions, each of which raises the atomic number by 1: so 4 beta particles are also emitted. Overall: 7 alpha pa …