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Chemistry · Ch 13 — Nuclear Chemistry and Radioactivity

Radioactivity

13.4

Radioactivity

An element is radioactive if the nuclei of its atoms are unstable. Radioactivity is the phenomenon in which such an unstable nucleus spontaneously emits a nuclear particle and/or gamma radiation and, in the process, transforms into a different nuclide -- elements such as uranium and radium are classic naturally radioactive elements.

A defining and important feature of radioactivity is that the probability of a given nucleus decaying does NOT depend on external, chemical-level conditions at all: it is unaffected by the state of chemical combination the atom happens to be in, by temperature, by pressure, by the presence of a catalyst, or even by how long that particular nucleus has already existed (its 'age'). This is a genuinely NUCLEAR phenomenon, governed entirely by what is happening inside the nucleus, and it is precisely this chemical-independence that distinguishes a nuclear reaction from an ordinary chemical one (see the comparison in section 13.7.1). …