Exercise · Q3
Q.Choose the most correct option.
A compound contains atoms of three elements A, B and C. If the oxidation state of A is +2, B is +5 and that of C is -2, the compound is possibly represented by
a. A2(BC3)2 b. A3(BC4)2 c. A3(B4C)2 d. ABC2
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✓ Free question
Step 1. Test (a) A2(BC3)2. Sum = 2(+2) + 2[(+5) + 3(-2)] = 4 + 2(5-6) = 4 - 2 = 2 ≠ 0. Rejected.
Step 2. Test (b) A3(BC4)2. Sum = 3(+2) + 2[(+5) + 4(-2)] = 6 + 2(5-8) = 6 - 6 = 0. Balances.
Step 3. Test (c) A3(B4C)2. Sum = 3(+2) + 2[4(+5) + (-2)] = 6 + 2(20-2) = 6 + 36 = 42 ≠ 0. Rejected.
Step 4. Test (d) ABC2. Sum = (+2) + (+5) + 2(-2) = 2 + 5 - 4 = 3 ≠ 0. Rejected.
Step 5. Only A3(BC4)2 gives an electrically neutral compound with A=+2, B=+5, C=-2, matching the pattern of a metal (A), a pentavalent central atom (B, like P or N in a phosphate/nitrate-type group) and oxygen-like C forming a polyatomic anion (BC4)⁻¹, three of which balance three A²⁺ ions.
✓Final answer
(b) A3(BC4)2
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