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Exercise · Q23

Q.Answer the following question.
Which of the following redox couple is stronger oxidizing agent?
a. Cl2 (E0 = 1.36 V) and Br2 (E0 = 1.09 V)
b. MnO4⁻ (E0 = 1.51 V) and Cr2O7²⁻ (E0 = 1.33 V)

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Step 1. Recall the rule. A more positive standard electrode potential (E0E^0) means a stronger tendency to be reduced, i.e. a stronger oxidising agent (Section 6.4.1).

Step 2. Compare (a). Cl2 has E0=1.36E^0 = 1.36 V; Br2 has E0=1.09E^0 = 1.09 V. Since 1.36 > 1.09, Cl2 is the stronger oxidising agent -- consistent with chlorine's well-known ability to displace bromide from its salts (Cl2 + 2Br⁻ → 2Cl⁻ + Br2). …

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