Exercise · Q23
Q.Answer the following question.
Which of the following redox couple is stronger oxidizing agent?
a. Cl2 (E0 = 1.36 V) and Br2 (E0 = 1.09 V)
b. MnO4⁻ (E0 = 1.51 V) and Cr2O7²⁻ (E0 = 1.33 V)
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Start your 14-day free trial to unlock the full solution →Step 1. Recall the rule. A more positive standard electrode potential () means a stronger tendency to be reduced, i.e. a stronger oxidising agent (Section 6.4.1).
Step 2. Compare (a). Cl2 has V; Br2 has V. Since 1.36 > 1.09, Cl2 is the stronger oxidising agent -- consistent with chlorine's well-known ability to displace bromide from its salts (Cl2 + 2Br⁻ → 2Cl⁻ + Br2). …
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