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Chemistry · Ch 4 — Structure of Atom

Postulates of Bohr Atomic Theory

4.6.1

Postulates of Bohr Atomic Theory

Niels Bohr's 1913 model for the hydrogen atom rests on four postulates. First, the electron can move around the nucleus only in one of several fixed circular paths of definite radius and definite energy; these permitted paths are called orbits, stationary states, or allowed energy states, and they are arranged concentrically around the nucleus in order of increasing energy. Second, the energy of an electron sitting in one of these orbits does not change with time — the electron only moves from a lower stationary state to a higher one if it absorbs exactly the right amount of energy, and only moves from a higher state to a lower one by emitting energy; this energy change always happens in a discontinuous jump, never gradually. Third — Bohr's frequency rule — when a transition occurs between two stationary states differing in energy by ΔE\Delta E, the frequency of the radiation absorbed or emitted is ν=E2−E1h\nu = \frac{E_2-E_1}{h}, where E1E_1 and E2E_2 are the energies of the lower and higher states respectively. Fourth, the electron's angular momentum in a given stationary state is restricted (quantised) to integral multiples of h2π\frac{h}{2\pi}: mvr=n×h2πmvr = n\times\frac{h}{2\pi} for n=1,2,3,…n = 1,2,3,\ldots — recalling that angular momentum for a particle moving on a circle of radius r at speed v works out to mvrmvr (moment of inertia I=mr2I=mr^2 tim …

Misc Angular momentum asideAngular momentum of a circular orbit

Worked out. A supporting note defining angular momentum, used in stating Bohr's fourth postulate. Angular momentum is the product of the moment of inertia (I) and the angular velocity (ω): angular momentum = I × ω. For a particle of mass m moving in a circle of radius r with linear speed v, I = mr² and ω = v/r, so angular momentum = mr² × (v/r) = mvr — the quantity Bohr's fourth postulate requires to be an integral multip …