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Chemistry · Ch 4 — Structure of Atom

Quantum Mechanical Model of Atom

4.7

Quantum Mechanical Model of Atom

Quantum mechanics — the branch of science built to satisfy both de Broglie's matter-wave duality and Heisenberg's uncertainty principle — was developed in 1926, independently, by Werner Heisenberg (starting from the uncertainty principle) and by Erwin Schrödinger (starting from wave motion). The wave-motion-based version, due to Schrödinger, is the one this chapter takes up. Schrödinger's fundamental equation of quantum mechanics, the Schrödinger (or wave) equation, is written H^ψ=Eψ\hat{H}\psi = E\psi, where H^\hat{H} is a mathematical operator called the Hamiltonian, ψ\psi (psi) is the wave function, and E is the total energy of the system. Actually solving this equation is beyond the scope of this ch …