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Chemistry · Ch 7 — Elements of Groups 16, 17 and 18

Xenon trioxide

7.13.2

Xenon trioxide

a. Preparation of Xenon trioxide (XeO3\mathrm{XeO_3}) : Fluorides of xenon react with water to form XeO3\mathrm{XeO_3}.

3XeF4+6H2O⟶2Xe+XeO3+12 HF+112 O2\mathrm{3XeF_4 + 6H_2O \longrightarrow 2Xe + XeO_3 + 12\,HF + 1\tfrac{1}{2}\,O_2}

XeF6+3H2O⟶XeO3+6HF\mathrm{XeF_6 + 3H_2O \longrightarrow XeO_3 + 6HF}

The first of these hydrolyses is a disproportionation: part of the xenon is reduced to the element while part is oxidised from the +4 to the +6 state in XeO3\mathrm{XeO_3} — which is why elemental xenon and oxygen appear alongside the trioxide. In the second, XeF6\mathrm{XeF_6} (already +6) exchanges all six fluorines for three oxygens without any change in oxidation state. The book writ …