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Problems · Problem 15.1

Q.Refer to the following table listing for different polymers formed from respective monomer. Identify from the list whether it is copolymer or homopolymer.
Sr. No. -- Monomer -- Polymer
  1. -- Ethylene -- Polyethylene
  2. -- Vinyl chloride -- Polyvinyl chloride
  3. -- Isobutylene -- Polyisobutylene
  4. -- Acrylonitrile -- Polyacrylonitrile
  5. -- Caprolactum -- Nylon 6
  6. -- Hexamethylene diammonium adipate -- Nylon 6, 6
  7. -- Butdiene + styrene -- Buna-S

Maharashtra MsbshseTextbookSubjectiveImportance★★★★★
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Step 1. Polyethylene (from ethylene), polyvinyl chloride (from vinyl chloride), polyisobutylene (from isobutylene), polyacrylonitrile (from acrylonitrile), and Nylon 6 (from caprolactam) are each formed from just one monomer, so all five are homopolymers.

Step 2. Nylon 6,6 starts from two different small molecules -- hexamethylenediamine and adipic acid -- but these first combine into a single salt, hexamethylene diammonium adipate, which is the true repeating monomer unit that then undergoes condensation; since there is really only one kind of repeating unit in the finished chain, Nylon 6,6 is also classed as a homopolymer. …

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