Chemistry · Ch 3 — Ionic Equilibria
Common ion effect
Common ion effect
Consider a solution of weak acid and its soluble ionic salt .
is weak acid, dissociates only slightly in solution
being a strong electrolyte dissociates almost completely in solution.
Both the acid and the salt produce ions in solution. dissociates completely. Therefore it provides high concentration of ions. According to Le-Chatelier principle, the addition of from to the solution of , shifts equilibrium of dissociation of to left. Thus reverse reaction is favoured in which combines with to form unionised . Hence dissociation of is suppressed due to presence of containing a common ion.
The common ion effect states that the ionisation of a weak electrolyte is suppressed in presence of a strong electrolyte containing an ion common to the weak electrolyte.
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