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Chemistry · Ch 3 — Ionic Equilibria

Common ion effect

3.10

Common ion effect

Consider a solution of weak acid CH3COOH\mathrm{CH_3COOH} and its soluble ionic salt CH3COONa\mathrm{CH_3COONa}.

CH3COOH\mathrm{CH_3COOH} is weak acid, dissociates only slightly in solution

CH3COOH⇌CH3COO−(aq)+H+(aq)\mathrm{CH_3COOH} \rightleftharpoons \mathrm{CH_3COO^{-}(aq)} + \mathrm{H^{+}(aq)}

CH3COONa\mathrm{CH_3COONa} being a strong electrolyte dissociates almost completely in solution.

CH3COONa(aq)→CH3COO−+Na+\mathrm{CH_3COONa(aq)} \rightarrow \mathrm{CH_3COO^{-}} + \mathrm{Na^{+}}

Both the acid and the salt produce CH3COO−\mathrm{CH_3COO^{-}} ions in solution. CH3COONa\mathrm{CH_3COONa} dissociates completely. Therefore it provides high concentration of CH3COO−\mathrm{CH_3COO^{-}} ions. According to Le-Chatelier principle, the addition of CH3COO−\mathrm{CH_3COO^{-}} from CH3COONa\mathrm{CH_3COONa} to the solution of CH3COOH\mathrm{CH_3COOH}, shifts equilibrium of dissociation of CH3COOH\mathrm{CH_3COOH} to left. Thus reverse reaction is favoured in which CH3COO−\mathrm{CH_3COO^{-}} combines with H+\mathrm{H^{+}} to form unionised CH3COOH\mathrm{CH_3COOH}. Hence dissociation of CH3COOH\mathrm{CH_3COOH} is suppressed due to presence of CH3COONa\mathrm{CH_3COONa} containing a common CH3COO−\mathrm{CH_3COO^{-}} ion.

The common ion effect states that the ionisation of a weak electrolyte is suppressed in presence of a strong electrolyte containing an ion common to the weak electrolyte.

Note

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