Chemistry · Ch 3 — Ionic Equilibria
Common ion effect and solubility
Common ion effect and solubility
The presence of a common ion also affects the solubility of a sparingly soluble salt. Consider, the solubility equilibrium of AgCl,
The solubility product of AgCl is
Suppose is added to the saturated solution of AgCl. The salt being a strong electrolyte dissociates completely in the solution.
The dissociation of AgCl and produce a common ion. The concentration of ion in the solution increases owing to complete dissociation of . According to Le-Chatelier's principle the addition of ions from to the solution of AgCl shifts the solubility equilibrium of AgCl from right to left. The reverse reaction in which AgCl precipitates, is favoured until the solubility equilibrium is re-established. The value of , however, remains the same since it is an equilibrium constant. The solubility of a sparingly soluble compound, thus decreases with the presence of a common ion in solution.
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