Chemistry · Ch 1 — Solid State
Number of particles in cubic unit cells
1.5.1
Number of particles in cubic unit cells
The number of particles that actually belong to a given unit cell depends on how each particle is shared with the neighbouring cells.
i. Primitive or simple cubic unit cell (sc) : A particle at a corner of a cube is shared among the 8 cubes that meet at that corner, so it contributes only of itself to any one cell. With particles at the 8 corners only, an sc cell contains 1 particle per unit cell.
ii. Body-centred cubic unit cell (bcc) : The 8 corner particles together contribute particle, and the particle at the body centre belongs to that cell alone, contributing a full 1. A bcc cell therefore contains a total of 2 particles per bcc unit cell. …