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Exercises · 9.13

Q.How does the atomic hydrogen or oxy-hydrogen torch function for cutting and welding purposes ? Explain.

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Atomic hydrogen torch: Two tungsten electrodes are maintained under a stream of hydrogen gas, and an electric arc is struck between them. The arc supplies enough energy to dissociate dihydrogen molecules into free hydrogen atoms:

H2(g)→electric arc2H(g)ΔH=+435.88 kJ mol−1H_2(g) \xrightarrow{electric\ arc} 2H(g) \qquad \Delta H = +435.88\ kJ\,mol^{-1}

This is a highly endothermic process — a large amount of energy is stored in the free atoms.

When this stream of atomic hydrogen is directed onto a metal surface to be welded/cut, the highly reactive H atoms recombine to reform stable H2 molecules right at that surface:

2H(g)→H2(g)2H(g) \rightarrow H_2(g)

This recombination releases the previously absorbed energy instantaneously and locally as intense heat — temperatures of roughly 4000 K can be achieved, sufficient to melt/fuse metals for welding or to cut through them.

Oxy-hydrogen torch: works on a related but simpler principle — dihydrogen gas is simply combusted with oxygen gas:

2H2(g)+O2(g)→2H2O(g)ΔH<02H_2(g) + O_2(g) \rightarrow 2H_2O(g) \qquad \Delta H < 0 …

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