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Worked Examples · Example 10.5

Q.Calculate the heat required to convert 3 kg3\ \text{kg} of ice at −12 ∘C-12\ ^\circ\text{C} kept in a calorimeter to steam at 100 ∘C100\ ^\circ\text{C} at atmospheric pressure. Given specific heat capacity of ice =2100 J kg−1 K−1= 2100\ \text{J kg}^{-1}\ \text{K}^{-1}, specific heat capacity of water =4186 J kg−1 K−1= 4186\ \text{J kg}^{-1}\ \text{K}^{-1}, latent heat of fusion of ice =3.35×105 J kg−1= 3.35 \times 10^{5}\ \text{J kg}^{-1} and latent heat of steam =2.256×106 J kg−1= 2.256 \times 10^{6}\ \text{J kg}^{-1}.

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Converting ice at −12∘-12^\circC to steam at 100∘100^\circC takes four separate steps - warming the ice, melting it, warming the water, then vaporising it - and the total heat required is 9.10×1069.10\times10^{6} J.

Ice cannot jump straight to steam; it must pass through every intermediate stage, and each stage needs its own heat calculation: Q=mcΔTQ=mc\Delta T for a temperature change, Q=mLQ=mL for a phase change.

Step 1 - Warm the ice from −12∘-12^\circC to 0∘0^\circC

Q1=m cice ΔT=3×2100×12=75,600 J.Q_1 = m\,c_{\text{ice}}\,\Delta T = 3\times2100\times12 = 75{,}600\ \text{J}.

Step 2 - Melt the ice at 0∘0^\circC

Q2=m Lf=3×3.35×105=1,005,000 J.Q_2 = m\,L_f = 3\times3.35\times10^{5} = 1{,}005{,}000\ \text{J}.

Step 3 - Warm the water from 0∘0^\circC to 100∘100^\circC

Q3=m cwater ΔT=3×4186×100=1,255,800 J.Q_3 = m\,c_{\text{water}}\,\Delta T = 3\times4186\times100 = 1{,}255{,}800\ \text{J}.

Step 4 - Vaporise the water at 100∘100^\circC

Q4=m Lv=3×2.256×106=6,768,000 J.Q_4 = m\,L_v = 3\times2.256\times10^{6} = 6{,}768{,}000\ \text{J}.

Total

Q=Q1+Q2+Q3+Q4=75,600+1,005,000+1,255,800+6,768,000=9,104,400 J.Q = Q_1+Q_2+Q_3+Q_4 = 75{,}600+1{,}005{,}000+1{,}255{,}800+6{,}768{,}000 = 9{,}104{,}400\ \text{J}. …

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