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Choose the Best Answer · Q7

Q.Find the wrong statement

a) sodium metal is used in organic qualitative analysis
b) sodium carbonate is soluble in water and it is used in inorganic qualitative analysis
c) potassium carbonate can be prepared by solvay process
d) potassium bicarbonate is acidic salt
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Step 1. Sodium metal is genuinely used in organic qualitative analysis (the sodium fusion / Lassaigne's test, used to detect N, S and halogens in organic compounds), so statement (a) is correct.

Step 2. Sodium carbonate is indeed water-soluble and its solution (soda extract) is used in inorganic qualitative salt analysis, so statement (b) is correct.

Step 3. The Solvay process depends on sodium bicarbonate being only sparingly soluble, so that it precipitates out of the ammoniacal brine and can be filtered off -- the analogous potassium bicarbonate, KHCO₃, is considerably MORE soluble and does not precipitate under the same conditions, so the Solvay process cannot be used to make potassium carbonate. Statement (c) is therefore the wrong (incorrect …

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