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Write Brief Answer · Q14

Q.Why alkaline earth metals are harder than alkali metals.

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Step 1. Metallic hardness and melting/boiling point both depend on the strength of the metallic bonding holding the lattice of metal cations and delocalised valence electrons together -- the stronger this attraction, the harder and higher-melting the metal.

Step 2. Alkaline earth metal atoms are smaller than the alkali metals of the same period (Section 5.5.1: higher nuclear charge pulls the electrons in more tightly), so their cations pack more closely together in the metallic lattice.

Step 3. Each alkaline earth metal atom also contributes TWO valence electrons to the shared 'sea' of delocalised electrons (ns²), compared to only ONE from each alkali metal atom (ns¹) -- doubling the electron density available to bind the lattice cations together. …

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