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Choose the Best Answer · Q18

Q.The variation of volume V, with temperature T, keeping pressure constant is called the coefficient of thermal expansion i.e. α=1V(∂V∂T)P\alpha=\dfrac{1}{V}\left(\dfrac{\partial V}{\partial T}\right)_P. For an ideal gas α\alpha is equal to

(a) T
(b) 1T\dfrac{1}{T}
(c) P
(d) none of these
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Step 1. For an ideal gas, V=nRTPV=\dfrac{nRT}{P}. Differentiating with respect to T at constant P: (∂V∂T)P=nRP\left(\dfrac{\partial V}{\partial T}\right)_P=\dfrac{nR}{P}.

Step 2. Since nRP=VT\dfrac{nR}{P}=\dfrac{V}{T} (rearranging the ideal gas equation), (∂V∂T)P=VT\left(\dfrac{\partial V}{\partial T}\right)_P=\dfrac{V}{T}. …

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