Write Brief Answer · Q29
Q.The stabilisation of a half filled d-orbital is more pronounced than that of the p-orbital. Why?
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Start your 14-day free trial to unlock the full solution →Step 1. Half-filled stabilisation comes from two effects: symmetrical charge distribution and exchange energy (section 2.6.5). Both scale with how many degenerate orbitals are available in the subshell.
Step 2. A p-subshell has 3 degenerate orbitals; when half-filled (), the number of possible pairwise exchanges among the 3 parallel-spin electrons is .
Step 3. A d-subshell has 5 degenerate orbitals; when half-filled (), the number of possible pairwise exchanges among the 5 parallel-spin electrons is . …
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