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II. Short Answer Questions · Q37

Q.If the piston of a container is pushed fast inward, will the ideal gas equation be valid in the intermediate stage? If not, why?

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Step 1. The ideal gas equation PV=NkTPV=NkT describes a system only when it is at thermodynamic equilibrium, with a single, well-defined pressure, volume and temperature throughout the gas.

Step 2. If the piston is pushed inward fast, the gas near the piston is compressed before the rest of the gas "knows" about it -- the pressure is momentarily higher near the piston than elsewhere, so the gas as a whole does not have one single well-defined pressure at that instant. …

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