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III. Long Answer Questions · Q3

Q.Explain in detail the thermal expansion.

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Step 1. Thermal expansion is the tendency of matter to change in shape, area and volume due to a temperature change. All three states of matter expand on heating, though gases expand the most (negligible intermolecular forces), liquids next, and solids the least (atoms simply vibrate with greater amplitude about fixed lattice points).

Step 2. Linear expansion: for a small ΔT\Delta T, the fractional change in length is ΔLL0=αLΔT\dfrac{\Delta L}{L_0}=\alpha_L\Delta T, so αL=ΔLL0ΔT\alpha_L=\dfrac{\Delta L}{L_0\Delta T} (coefficient of linear expansion, unit °C⁻¹ or K⁻¹).

Step 3. Area expansion: ΔAA0=αAΔT\dfrac{\Delta A}{A_0}=\alpha_A\Delta T. Volume expansion: ΔVV0=αVΔT\dfrac{\Delta V}{V_0}=\alpha_V\Delta T. For the same specimen, αA≈2αL\alpha_A\approx2\alpha_L and αV≈3αL\alpha_V\approx3\alpha_L.

Step 4. Real consequences: railway tracks and bridges have small expansion gaps/joints so they can lengthen in summer heat without buckling (worked in Example 8.6 for the Eiffel Tower's height change between winter and summer); a tight glass-bottle lid loosens in hot water because it expands more than the glass; a boiled egg's shell separates easily in cold water because the shell and egg contract by different amounts.

✓Final answer

Thermal expansion follows ΔL/L0=αLΔT\Delta L/L_0=\alpha_L\Delta T, ΔA/A0=αAΔT\Delta A/A_0=\alpha_A\Delta T, ΔV/V0=αVΔT\Delta V/V_0=\alpha_V\Delta T (with αA≈2αL\alpha_A\approx2\alpha_L, αV≈3αL\alpha_V\approx3\alpha_L), strongest in gases, weakest in solids, with everyday consequences like railway expansion gaps.

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