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NCERT Exemplar · Q11

Q.A device operates between a hot reservoir at temperature T1T_1 (drawn at the top) and a cold reservoir at temperature T2T_2 (drawn at the bottom). In one cycle Q1Q_1 is the heat added to the hot bath T1T_1 (the heat delivered by the device to T1T_1) and Q2Q_2 is the heat taken from the cold bath T2T_2 (the heat drawn by the device from T2T_2). WW is the mechanical work done on the device. If W>0W>0, which of the following are possible? More than one of the options may be correct.

(a) Q1>Q2>0Q_1 > Q_2 > 0
(b) Q2>Q1>0Q_2 > Q_1 > 0
(c) Q2<Q1<0Q_2 < Q_1 < 0
(d) Q1<0, Q2>0Q_1 < 0,\ Q_2 > 0
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With Q1Q_1 the heat delivered to the hot bath, Q2Q_2 the heat drawn from the cold bath and WW the work done on the device, conservation of energy over a cycle (ΔU=0\Delta U=0) reads Q1=Q2+WQ_1=Q_2+W. Since W>0W>0, we need Q1>Q2Q_1>Q_2. That inequality holds both when both are positive (A) and when both are negative with Q1Q_1 less negative (C).

Concept

Over one complete cycle the device returns to its initial state, so ΔU=0\Delta U=0 and the first law gives, for the stated sign convention (energy in == energy out):

W+Q2=Q1⟹Q1−Q2=W.W+Q_2=Q_1\quad\Longrightarrow\quad Q_1-Q_2=W.

Applying W>0W>0

W>0⇒Q1−Q2>0⇒Q1>Q2W>0\Rightarrow Q_1-Q_2>0\Rightarrow Q_1>Q_2. Now test the options:

  • (A) Q1>Q2>0Q_1>Q_2>0: satisfies Q1>Q2Q_1>Q_2 — possible. …

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