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NCERT Exemplar · Q24

Q.An engine made of one mole of a perfect gas in a cylinder with a piston is taken once around the cycle A→B→C→D→AA\to B\to C\to D\to A on a PP-VV diagram, where A→BA\to B is at constant volume, B→CB\to C is adiabatic, C→DC\to D is at constant volume and D→AD\to A is adiabatic. The volumes satisfy VC=VD=2VA=2VBV_C=V_D=2V_A=2V_B, so states AA and BB share the smaller volume VAV_A and states CC and DD share the larger volume 2VA2V_A. On the diagram AA is the lower-left corner with BB directly above it (same volume VAV_A, higher pressure PB>PAP_B>P_A); CC is at the upper-right and DD directly below it (both at volume 2VA2V_A), with the adiabatic B→CB\to C expanding the gas and the adiabatic D→AD\to A compressing it. Take γ=53\gamma=\tfrac{5}{3} and Cv=32RC_v=\tfrac{3}{2}R for the one mole of gas.

(a) In which part of the cycle is heat supplied to the engine from outside?
(b) In which part of the cycle is heat given to the surroundings by the engine?
(c) Find the work done by the engine in one cycle, in terms of PAP_A, PBP_B and VAV_A.
(d) Find the efficiency of the engine.
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Only the two constant-volume legs exchange heat: A→BA\to B absorbs heat (pressure and temperature rise) and C→DC\to D rejects heat. The adiabats B→CB\to C and D→AD\to A carry no heat but do the work. Adding the two adiabatic works gives W=32(PB−PA)VA[1−2−2/3]≈0.55(PB−PA)VAW=\tfrac32(P_B-P_A)V_A[1-2^{-2/3}]\approx0.55(P_B-P_A)V_A, and dividing by the absorbed heat gives η=1−2−2/3≈37%\eta=1-2^{-2/3}\approx37\%.

Setup

Using the adiabatic relation PVγ=PV^{\gamma}=const on the two adiabats (with volume ratio 2):

B→C: PC=PB2γ,D→A: PD=PA2γ.B\to C:\ P_C=\frac{P_B}{2^{\gamma}},\qquad D\to A:\ P_D=\frac{P_A}{2^{\gamma}}.

(a) Heat supplied from outside

A→BA\to B is at constant volume with PB>PAP_B>P_A, so temperature rises and QAB=Cv(TB−TA)>0Q_{AB}=C_v(T_B-T_A)>0: heat is supplied during A→BA\to B.

(b) Heat rejected to surroundings

C→DC\to D is at constant volume with PC>PDP_C>P_D, so temperature falls and QCD=Cv(TD−TC)<0Q_{CD}=C_v(T_D-T_C)<0: heat is given to the surroundings during C→DC\to D. (The adiabats B→CB\to C and D→AD\to A exchange no heat.)

(c) Work done in one cycle

Constant-volume legs do no work, so W=WBC+WDAW=W_{BC}+W_{DA}, with adiabatic work W=PiVi−PfVfγ−1W=\dfrac{P_iV_i-P_fV_f}{\gamma-1}:

WBC=PBVA−PC(2VA)γ−1,WDA=PD(2VA)−PAVAγ−1.W_{BC}=\frac{P_BV_A-P_C(2V_A)}{\gamma-1},\qquad W_{DA}=\frac{P_D(2V_A)-P_AV_A}{\gamma-1}.

Adding and substituting PC=PB2−γP_C=P_B2^{-\gamma}, PD=PA2−γP_D=P_A2^{-\gamma}:

W=VAγ−1[(PB−PA)−2⋅2−γ(PB−PA)]=VA(PB−PA)γ−1(1−21−γ).W=\frac{V_A}{\gamma-1}\Big[(P_B-P_A)-2\cdot2^{-\gamma}(P_B-P_A)\Big]=\frac{V_A(P_B-P_A)}{\gamma-1}\big(1-2^{1-\gamma}\big). …

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