Chemistry · Class 11 Science
Ch 3Classification of Elements and Periodicity in Properties — Class 11 Chemistry, concept-first.
Nobel laureate Glenn T. Seaborg once described the Periodic Table as one of the most important ideas in all of chemistry — not just a reference chart, but a map that reveals how chemical elements are organised into families with recurring, predictable properties.
Key concepts
Hover a concept to preview it and jump to its most relevant Q&A.
Element Nomenclature
Imagine you discover a new island. You can't just call it "that place" — you need a name, a symbol on a map, and a way to write it in official documents. The same happens when scientists discover a new element.
Most relevant Q&A
- What would be the IUPAC name and symbol for the element with atomic number 120?Preview
- Which element do you think would have been named by (i) Lawrence Berkeley Laboratory (ii) Seaborg's group?Preview
- Identify the group and valency of the element having atomic number 119. Also predict the outermost electronic configuration and write the ge…Preview
Chapter contents
The NCERT structure, section by section. Open a section to see its questions, then read the concept-first solution.
Introduction
Nobel laureate Glenn T. Seaborg once described the Periodic Table as one of the most important ideas in all of chemistry — not just a reference chart, but a map that reveals how chemical elements are…
Why do we need to Classify Elements?
By 1800, chemists knew only 31 elements. By 1865, that number had jumped to 63. Today, we know 114 elements, and the most recent ones are man-made — created in laboratories through nuclear reactions.
Genesis of Periodic Classification
The modern Periodic Table did not appear overnight. It is the product of nearly a century of observations, guesses, corrections, and bold predictions by several scientists.
Modern Periodic Law and the Present Form of the Periodic Table
Mendeleev's periodic law stated that the properties of elements are a periodic function of their atomic masses.
Nomenclature of Elements with Atomic Numbers > 100
For most of chemistry's history, the discoverer of a new element had the privilege of naming it, subject to ratification by the International Union of Pure and Applied Chemistry (IUPAC).
Electronic Configurations of Elements and the Periodic Table
The distribution of electrons into the orbitals of an atom is called its electronic configuration. The position of an element in the Periodic Table is directly linked to the quantum numbers of the las…
Electronic Configurations and Types of Elements: s-, p-, d-, f-Blocks
The Aufbau principle and each element's electronic configuration give a solid theoretical footing for periodic classification.
The s-Block Elements
The s-block of the periodic table consists of two groups: Group 1 (the alkali metals) and Group 2 (the alkaline earth metals).
The p-Block Elements
The p-block is the right-hand block of the periodic table, spanning Groups 13 through 18. Together with the s-block elements (Groups 1 and 2), these are called the Representative Elements or Main Grou…
The d-Block Elements (Transition Elements)
The d-block elements occupy Groups 3 through 12 in the centre of the Periodic Table. Their defining feature is the filling of inner d orbitals with electrons — specifically, the subshell.
The f-Block Elements (Inner-Transition Elements)
The periodic table places two rows of elements separately at the bottom: the Lanthanoids (Cerium, Z = 58, to Lutetium, Z = 71) and the Actinoids (Thorium, Z = 90, to Lawrencium, Z = 103).
Metals, Non-metals and Metalloids
The periodic table groups elements not only into s, p, d, and f blocks, but also into three broad categories based on their physical and chemical properties: metals, non-metals, and metalloids (also c…
Periodic Trends in Properties of Elements
The periodic table is not just a catalogue of elements — it is a map of repeating patterns. As you move down a group or across a period, physical and chemical properties change in predictable ways.
Trends in Physical Properties
The periodic table is not just a list of elements; it is a map of how atoms behave. The physical properties of elements — their size, the energy needed to remove an electron, the energy released when…
+−Problemsi3 questions
- Problem 3.5Which of the following species will have the largest and the smallest size? $Mg,\ Mg^{2+},\ Al,\ Al^{3+}$.Free
- Problem 3.6The first ionization enthalpy ($\Delta_i H$) values of the third period elements, Na, Mg and Si are respectively 496, 737 and 786 kJ mol$^{-…Preview
- Problem 3.7Which of the following will have the most negative electron gain enthalpy and which the least negative? P, S, Cl, F. Explain your answer.Preview
(a) Atomic Radius
Measuring the size of an atom is not like measuring the radius of a ball. There are two fundamental difficulties. First, an atom is incredibly small — its radius is on the order of m (or 1.2 Å).
(b) Ionic Radius
When an atom loses an electron to form a cation (a positive ion), its size decreases. The nuclear charge remains the same, but there are now fewer electrons.
(c) Ionization Enthalpy
Ionization enthalpy () is a quantitative measure of the tendency of an element to lose an electron. It is defined as the energy required to remove the most loosely bound electron from an isolated gase…
(d) Electron Gain Enthalpy
Electron gain enthalpy () is the enthalpy change that occurs when an electron is added to a neutral, isolated gaseous atom to form a negative ion.
(e) Electronegativity
Electronegativity is a qualitative measure of the ability of an atom in a chemical compound to attract shared electrons to itself.
Periodic Trends in Chemical Properties
The chemical behaviour of elements follows predictable patterns across the periodic table. Two major themes emerge: the periodicity of valence (or oxidation states), and the anomalous properties of th…
(a) Periodicity of Valence or Oxidation States
Valence is the most characteristic property of an element. For representative (s- and p-block) elements, the valence is usually equal to either the number of electrons in the outermost shell or eight…
(b) Anomalous Properties of Second Period Elements
The first element of each group — lithium (group 1), beryllium (group 2), and boron through fluorine (groups 13–17) — differs significantly from the other members of its group.
Periodic Trends and Chemical Reactivity
The periodic table is not just an arrangement of elements — it is a map of chemical behaviour. Every physical and chemical property of an element ultimately stems from its electronic configuration.
Summary
- Moseley’s law established that atomic number (), not atomic mass, is the fundamental property determining element identity.
Exercises
This closing exercise set gives you 40 questions covering everything in the unit — from the historical development of the Periodic Table and the IUPAC naming of superheavy elements, to electronic conf…
+−Exercisesi40 questions
- 3.1What is the basic theme of organisation in the periodic table?Free
- 3.2Which important property did Mendeleev use to classify the elements in his periodic table and did he stick to that?Free
- 3.3What is the basic difference in approach between the Mendeleev's Periodic Law and the Modern Periodic Law?Free
- 3.4On the basis of quantum numbers, justify that the sixth period of the periodic table should have 32 elements.Preview
- 3.5In terms of period and group where would you locate the element with $Z = 114$?Preview
- 3.6Write the atomic number of the element present in the third period and seventeenth group of the periodic table.Preview
- 3.7Which element do you think would have been named by (i) Lawrence Berkeley Laboratory (ii) Seaborg's group?Preview
- 3.8Why do elements in the same group have similar physical and chemical properties?Preview
- 3.9What does atomic radius and ionic radius really mean to you?Preview
- 3.10How do atomic radius vary in a period and in a group? How do you explain the variation?Preview
- 3.11What do you understand by isoelectronic species? Name a species that will be isoelectronic with each of the following atoms or ions. (i) $F^…Preview
- 3.12Consider the following species: $N^{3-}, O^{2-}, F^-, Na^+, Mg^{2+}$ and $Al^{3+}$. (a) What is common in them? (b) Arrange them in the orde…Preview
- 3.13Explain why cations are smaller and anions larger in radii than their parent atoms?Preview
- 3.14What is the significance of the terms — 'isolated gaseous atom' and 'ground state' while defining the ionization enthalpy and electron gain…Preview
- 3.15Energy of an electron in the ground state of the hydrogen atom is $-2.18 \times 10^{-18}$ J. Calculate the ionization enthalpy of atomic hyd…Preview
- 3.16Among the second period elements the actual ionization enthalpies are in the order Li < B < Be < C < O < N < F < Ne. Explain why (i) Be has…Preview
- 3.17How would you explain the fact that the first ionization enthalpy of sodium is lower than that of magnesium but its second ionization enthal…Preview
- 3.18What are the various factors due to which the ionization enthalpy of the main group elements tends to decrease down a group?Preview
- 3.19The first ionization enthalpy values (in kJ mol$^{-1}$) of group 13 elements are: B 801, Al 577, Ga 579, In 558, Tl 589. How would you expla…Preview
- 3.20Which of the following pairs of elements would have a more negative electron gain enthalpy? (i) O or F (ii) F or ClPreview
- 3.21Would you expect the second electron gain enthalpy of O as positive, more negative or less negative than the first? Justify your answer.Preview
- 3.22What is the basic difference between the terms electron gain enthalpy and electronegativity?Preview
- 3.23How would you react to the statement that the electronegativity of N on Pauling scale is 3.0 in all the nitrogen compounds?Preview
- 3.24Describe the theory associated with the radius of an atom as it (a) gains an electron (b) loses an electron.Preview
- 3.25Would you expect the first ionization enthalpies for two isotopes of the same element to be the same or different? Justify your answer.Preview
- 3.26What are the major differences between metals and non-metals?Preview
- 3.27Use the periodic table to answer the following questions. (a) Identify an element with five electrons in the outer subshell. (b) Identify an…Preview
- 3.28The increasing order of reactivity among group 1 elements is Li < Na < K < Rb < Cs whereas that among group 17 elements is F > Cl > Br > I.…Preview
- 3.29Write the general outer electronic configuration of s-, p-, d- and f-block elements.Preview
- 3.30Assign the position of the element having outer electronic configuration (i) $ns^2 np^4$ for $n=3$ (ii) $(n-1)d^2 ns^2$ for $n=4$, and (iii)…Preview
- 3.31The first ($\Delta_i H_1$) and the second ($\Delta_i H_2$) ionization enthalpies (in kJ mol$^{-1}$) and the ($\Delta_{eg}H$) electron gain e…Preview
- 3.32Predict the formulas of the stable binary compounds that would be formed by the combination of the following pairs of elements. (a) Lithium…Preview
- 3.33In the modern periodic table, the period indicates the value of: (a) atomic number (b) atomic mass (c) principal quantum number (d) azimutha…Preview
- 3.34Which of the following statements related to the modern periodic table is incorrect? (a) The p-block has 6 columns, because a maximum of 6 e…Preview
- 3.35Anything that influences the valence electrons will affect the chemistry of the element. Which one of the following factors does not affect…Preview
- 3.36The size of isoelectronic species — $F^-$, Ne and $Na^+$ is affected by (a) nuclear charge (Z) (b) valence principal quantum number (n) (c)…Preview
- 3.37Which one of the following statements is incorrect in relation to ionization enthalpy? (a) Ionization enthalpy increases for each successive…Preview
- 3.38Considering the elements B, Al, Mg, and K, the correct order of their metallic character is: (a) B > Al > Mg > K (b) Al > Mg > B > K (c) Mg…Preview
- 3.39Considering the elements B, C, N, F, and Si, the correct order of their non-metallic character is: (a) B > C > Si > N > F (b) Si > C > B > N…Preview
- 3.40Considering the elements F, Cl, O and N, the correct order of their chemical reactivity in terms of oxidizing property is: (a) F > Cl > O >…Preview
NCERT Exemplar
Higher-order thinking problems from the NCERT Exemplar.
+−Show 59 questionsHide questions59 questions
- Q1Consider the isoelectronic species, Na^+, Mg^2+, F^- and O^2-. The correct order of increasing length of their radii is _________. (i) F^- <…Free
- Q2Which of the following is not an actinoid? (i) Curium (Z = 96) (ii) Californium (Z = 98) (iii) Uranium (Z = 92) (iv) Terbium (Z = 65)Free
- Q3The order of screening effect of electrons of s, p, d and f orbitals of a given shell of an atom on its outer shell electrons is: (i) s > p…Free
- Q4The first ionisation enthalpies of Na, Mg, Al and Si are in the order: (i) Na < Mg > Al < Si (ii) Na > Mg > Al > Si (iii) Na < Mg < Al < Si…Preview
- Q5The electronic configuration of gadolinium (Atomic number 64) is (i) [Xe] 4f^3 5d^5 6s^2 (ii) [Xe] 4f^7 5d^2 6s^1 (iii) [Xe] 4f^7 5d^1 6s^2…Preview
- Q6The statement that is not correct for periodic classification of elements is: (i) The properties of elements are periodic function of their…Preview
- Q7Among halogens, the correct order of amount of energy released in electron gain (electron gain enthalpy) is: (i) F > Cl > Br > I (ii) F < Cl…Preview
- Q8The period number in the long form of the periodic table is equal to (i) magnetic quantum number of any element of the period. (ii) atomic n…Preview
- Q9The elements in which electrons are progressively filled in 4f-orbital are called (i) actinoids (ii) transition elements (iii) lanthanoids (…Preview
- Q10Which of the following is the correct order of size of the given species: (i) I > I^- > I^+ (ii) I^+ > I^- > I (iii) I > I^+ > I^- (iv) I^-…Preview
- Q11The formation of the oxide ion, O^2- (g), from oxygen atom requires first an exothermic and then an endothermic step as shown below: O (g) +…Preview
- Q12Comprehension given below is followed by some multiple choice questions. Each question has one correct option. Choose the correct option. In…Preview
- Q13(b) The last element of the p-block in 6th period is represented by the outermost electronic configuration. (i) 7s^2 7p^6 (ii) 5f^14 6d^10 7…Preview
- Q14(c) Which of the elements whose atomic numbers are given below, cannot be accommodated in the present set up of the long form of the periodi…Preview
- Q15(d) The electronic configuration of the element which is just above the element with atomic number 43 in the same group is ________. (i) 1s^…Preview
- Q16(e) The elements with atomic numbers 35, 53 and 85 are all ________. (i) noble gases (ii) halogens (iii) heavy metals (iv) light metalsPreview
- Q17Electronic configurations of four elements A, B, C and D are given below: (A) 1s^2 2s^2 2p^6 (B) 1s^2 2s^2 2p^4 (C) 1s^2 2s^2 2p^6 3s^1 (D)…Preview
- Q18Which of the following elements can show covalency greater than 4? (Note: more than one of the given options may be correct.) (i) Be (ii) P…Preview
- Q19Those elements impart colour to the flame on heating in it, the atoms of which require low energy for the ionisation (i.e., absorb energy in…Preview
- Q20Which of the following sequences contain atomic numbers of only representative elements? (Note: more than one of the given options may be co…Preview
- Q21Which of the following elements will gain one electron more readily in comparison to other elements of their group? (Note: more than one of…Preview
- Q22Which of the following statements are correct? (Note: more than one of the given options may be correct.) (i) Helium has the highest first i…Preview
- Q23Which of the following sets contain only isoelectronic ions? (Note: more than one of the given options may be correct.) (i) Zn^2+, Ca^2+, Ga…Preview
- Q24In which of the following options order of arrangement does not agree with the variation of property indicated against it? (Note: more than…Preview
- Q25Which of the following have no unit? (Note: more than one of the given options may be correct.) (i) Electronegativity (ii) Electron gain ent…Preview
- Q26Ionic radii vary in (Note: more than one of the given options may be correct.) (i) inverse proportion to the effective nuclear charge. (ii)…Preview
- Q27An element belongs to 3rd period and group-13 of the periodic table. Which of the following properties will be shown by the element? (Note:…Preview
- Q28Explain why the electron gain enthalpy of fluorine is less negative than that of chlorine.Preview
- Q29All transition elements are d-block elements, but all d-block elements are not transition elements. Explain.Preview
- Q30Identify the group and valency of the element having atomic number 119. Also predict the outermost electronic configuration and write the ge…Preview
- Q31Ionisation enthalpies of elements of second period are given below: Ionisation enthalpy/ k cal mol$^{-1}$: 520, 899, 801, 1086, 1402, 1314,…Preview
- Q32Among the elements B, Al, C and Si, (i) which element has the highest first ionisation enthalpy? (ii) which element has the most metallic ch…Preview
- Q33Write four characteristic properties of p-block elements.Preview
- Q34Choose the correct order of atomic radii of fluorine and neon (in pm) out of the options given below and justify your answer. (i) 72, 160 (i…Preview
- Q35Illustrate by taking examples of transition elements and non-transition elements that oxidation states of elements are largely based on elec…Preview
- Q36Nitrogen has positive electron gain enthalpy whereas oxygen has negative. However, oxygen has lower ionisation enthalpy than nitrogen. Expla…Preview
- Q37First member of each group of representative elements (i.e., s and p-block elements) shows anomalous behaviour. Illustrate with two examples…Preview
- Q38p-Block elements form acidic, basic and amphoteric oxides. Explain each property by giving two examples and also write the reactions of thes…Preview
- Q39How would you explain the fact that first ionisation enthalpy of sodium is lower than that of magnesium but its second ionisation enthalpy i…Preview
- Q40What do you understand by exothermic reaction and endothermic reaction? Give one example of each type.Preview
- Q41Arrange the elements N, P, O and S in the order of- (i) increasing first ionisation enthalpy. (ii) increasing non metallic character. Give r…Preview
- Q42Explain the deviation in ionisation enthalpy of some elements from the general trend by using Fig. 3.2. ![Complete labelled graph of first i…Preview
- Q43Explain the following: (a) Electronegativity of elements increase on moving from left to right in the periodic table. (b) Ionisation enthalp…Preview
- Q44How does the metallic and non metallic character vary on moving from left to right in a period?Preview
- Q45The radius of Na^+ cation is less than that of Na atom. Give reason.Preview
- Q46Among alkali metals which element do you expect to be least electronegative and why?Preview
- Q47Match the correct atomic radius with the element. Element | Atomic radius (pm) Be | 74 C | 88 O | 111 B | 77 N | 66Preview
- Q48Match the correct ionisation enthalpies and electron gain enthalpies of the following elements. Elements: (i) Most reactive non metal (ii) M…Preview
- Q49Electronic configuration of some elements is given in Column I and their electron gain enthalpies are given in Column II. Match the electron…Preview
- Q50Assertion (A): Generally, ionisation enthalpy increases from left to right in a period. Reason (R): When successive electrons are added to t…Preview
- Q51Assertion (A): Boron has a smaller first ionisation enthalpy than beryllium. Reason (R): The penetration of a 2s electron to the nucleus is…Preview
- Q52Assertion (A): Electron gain enthalpy becomes less negative as we go down a group. Reason (R): Size of the atom increases on going down the…Preview
- Q53Discuss the factors affecting electron gain enthalpy and the trend in its variation in the periodic table.Preview
- Q54Define ionisation enthalpy. Discuss the factors affecting ionisation enthalpy of the elements and its trends in the periodic table.Preview
- Q55Justify the given statement with suitable examples— "the Properties of the elements are a periodic function of their atomic numbers".Preview
- Q56Write down the outermost electronic configuration of alkali metals. How will you justify their placement in group 1 of the periodic table?Preview
- Q57Write the drawbacks in Mendeleev's periodic table that led to its modification.Preview
- Q58In what manner is the long form of periodic table better than Mendeleev's periodic table? Explain with examples.Preview
- Q59Discuss and compare the trend in ionisation enthalpy of the elements of group 1 with those of group 17 elements.Preview