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Write Brief Answer · Q7

Q.Explain the following observations

(a) Aerated water bottles are kept under water during summer
(b) Liquid ammonia bottle is cooled before opening the seal
(c) The tyre of an automobile is inflated to slightly lesser pressure in summer than in winter
(d) The size of a weather balloon becomes larger and larger as it ascends up into larger altitude
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Step 1 (a). An aerated water bottle contains dissolved CO2_2 under pressure; kept underwater in summer, it stays cool, which (by Gay-Lussac's law, at the bottle's essentially fixed volume) keeps its internal pressure from rising as high as it would in the hot summer air -- reducing the risk of the bottle bursting.

Step 2 (b). A liquid ammonia bottle is cooled before its seal is opened because cooling lowers the vapour pressure of the ammonia trapped above the liquid, making the release, when the seal is broken, far gentler and safer than it would be at a higher (uncooled) pressure.

Step 3 (c). A tyre is inflated to slightly lower pressure in summer because the trapped air will itself heat up on a hot day and its pressure will rise (Gay-Lussac's law, constant volume) -- starting a little lower in summer avoids ending up dangerously over-pressurised once the tyre warms up. …

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