Q.Why interstitial hydrides have a lower density than the parent metal.
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Start your 14-day free trial to unlock the full solution →Step 1. In an interstitial (metallic) hydride, hydrogen atoms enter the interstitial sites (voids) that already exist between the metal atoms of the parent lattice -- they are not inserted by replacing or displacing metal atoms.
Step 2. Accommodating these extra hydrogen atoms, however, generally causes the metal lattice to expand slightly outward, since the interstitial voids were not originally sized to hold guest atoms.
Step 3. Density is mass divided by volume. Absorbing hydrogen adds only a small amount of extra mass (hydrogen is the lightest element) but causes a comparatively larger increase in the metal's overall volume (due to lattice expansion). …
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