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Write Brief Answer · Q23

Q.Briefly give the basis for pauling's scale of electronegativity.

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Step 1. Electronegativity cannot be measured directly, so Pauling built a numerical scale instead. He started by arbitrarily assigning hydrogen an electronegativity of 2.1 and fluorine 4.0.

Step 2. For any other bonded pair A-B, he calculated the DIFFERENCE in their electronegativities from the 'extra' bond dissociation energy of the real A-B bond compared to what a purely non-polar (average of A-A and B-B) bond would have:

(χA−χB)=0.182EAB−EAA×EBB(\chi_A - \chi_B) = 0.182\sqrt{E_{AB} - \sqrt{E_{AA}\times E_{BB}}}

where EAB,EAA,EBBE_{AB}, E_{AA}, E_{BB} are the bond dissociation energies (kcal) of AB, A2 and B2 respectively. …

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