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Choose the Best Answer · Q5

Q.In an adiabatic expansion of an ideal gas

(a) w=−Δuw = -\Delta u
(b) w=Δu+ΔHw = \Delta u + \Delta H
(c) Δu=0\Delta u = 0
(d) w=0w = 0
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Step 1. This question uses work ww in the sense of work done BY the expanding gas (the convention several other Indian textbooks and exam banks use, i.e. ΔU=q−w\Delta U=q-w), rather than this chapter's own IUPAC convention (ΔU=q+w\Delta U=q+w, ww = work done ON the system, Section 7.4.1).

Step 2. Under ΔU=q−w\Delta U=q-w with q=0q=0 (adiabatic): ΔU=−w⇒w=−ΔU\Delta U=-w \Rightarrow w=-\Delta U -- the gas does positive work on its surroundings exactly as its own internal energy falls. …

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