Q.Differentiate crystalline solids and amorphous solids.
Step 1. Arrangement of constituents: crystalline solids have a long-range, orderly arrangement of their constituents; amorphous solids have only a short-range, random arrangement.
Step 2. Shape: crystalline solids have a definite geometric shape; amorphous solids have an irregular shape.
Step 3. Isotropy: crystalline solids are generally anisotropic (physical properties differ with measurement direction); amorphous solids are isotropic, like liquids.
Step 4. Nature: crystalline solids are considered TRUE solids; amorphous solids are considered pseudo-solids, or supercooled liquids.
Step 5. Heat of fusion: crystalline solids have a definite heat of fusion; amorphous solids do not.
Step 6. Melting behaviour: crystalline solids have sharp, definite melting points; amorphous solids gradually soften over a range of temperature (which is why they can be moulded). Examples: NaCl, diamond (crystalline) vs rubber, plastics, glass (amorphous).
Crystalline solids show long-range order, definite shape, anisotropy, a definite heat of fusion and a sharp melting point (e.g. NaCl, diamond); amorphous solids show only short-range/random order, irregular shape, isotropy, no definite heat of fusion, and gradual softening over a temperature range instead of a sharp melting point (e.g. glass, rubber, plastics).
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