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Exercises · 8.2

Q.In the Bohr atom model, the frequency of transitions is given by v=Rc(1n2−1m2)v=Rc\left(\dfrac{1}{n^2}-\dfrac{1}{m^2}\right), where n<mn<m. Consider the three transitions m=3→n=2m=3\to n=2, m=2→n=1m=2\to n=1 and m=3→n=1m=3\to n=1. Show that the frequencies of these transitions obey the sum rule (known as the Ritz combination principle).

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✓ Free question

Step 1. Define, for any level kk, the quantity f(k)=Rc/k2f(k)=Rc/k^2; then the transition frequency between any two levels m>nm>n is simply vm→n=f(n)−f(m)v_{m\to n}=f(n)-f(m).

Step 2. For the three specified transitions: v3→2=f(2)−f(3)v_{3\to2}=f(2)-f(3), v2→1=f(1)−f(2)v_{2\to1}=f(1)-f(2), and v3→1=f(1)−f(3)v_{3\to1}=f(1)-f(3).

Step 3. Adding the first two: v3→2+v2→1=[f(2)−f(3)]+[f(1)−f(2)]=f(1)−f(3)v_{3\to2}+v_{2\to1}=[f(2)-f(3)]+[f(1)-f(2)]=f(1)-f(3).

Step 4. This is exactly equal to v3→1=f(1)−f(3)v_{3\to1}=f(1)-f(3) found in Step 2. So

v3→1=v3→2+v2→1v_{3\to1}=v_{3\to2}+v_{2\to1}

confirming that the frequency of the direct 3→13\to1 transition equals the sum of the frequencies of the two-step 3→2→13\to2\to1 path - the Ritz combination principle.

Step 5. This result holds for any three levels n<p<mn<p<m by exactly the same telescoping argument, and is a direct, testable consequence of the fact that spectral frequencies are simply differences of an underlying ladder of atomic energy levels.

✓Final answer

v3→1=v3→2+v2→1v_{3\to1}=v_{3\to2}+v_{2\to1}, confirmed by telescoping the level-energy differences.

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